catena-Poly[[[triaqua­(nitrato-κ(2) O,O′)neodymium(III)]-bis­(μ(2)-pyridinium-4-carboxyl­ato-κ(2) O:O′)] bis­(perchlorate) monohydrate]

In the title compound, {[Nd(NO(3))(C(6)H(5)NO(2))(2)(H(2)O)(3)](ClO(4))(2)·H(2)O}(n), the Nd(III) atom is nine-coordinated by four O atoms from four pyridinium-4-carboxyl­ate ligands, two O atoms from a chelating nitrate anion and three water mol­ecules in a distorted tricapped trigonal–prismatic co...

Descripción completa

Detalles Bibliográficos
Autor principal: Pu, Jia-Zhi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968357/
https://www.ncbi.nlm.nih.gov/pubmed/21581760
http://dx.doi.org/10.1107/S1600536808043997
_version_ 1782189850923892736
author Pu, Jia-Zhi
author_facet Pu, Jia-Zhi
author_sort Pu, Jia-Zhi
collection PubMed
description In the title compound, {[Nd(NO(3))(C(6)H(5)NO(2))(2)(H(2)O)(3)](ClO(4))(2)·H(2)O}(n), the Nd(III) atom is nine-coordinated by four O atoms from four pyridinium-4-carboxyl­ate ligands, two O atoms from a chelating nitrate anion and three water mol­ecules in a distorted tricapped trigonal–prismatic coordination geometry. Adjacent Nd atoms are linked by the bidentate pyridinium-4-carboxyl­ate ligands into a chain running along the b axis. The chains are further connected by O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network.
format Text
id pubmed-2968357
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29683572010-12-30 catena-Poly[[[triaqua­(nitrato-κ(2) O,O′)neodymium(III)]-bis­(μ(2)-pyridinium-4-carboxyl­ato-κ(2) O:O′)] bis­(perchlorate) monohydrate] Pu, Jia-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Nd(NO(3))(C(6)H(5)NO(2))(2)(H(2)O)(3)](ClO(4))(2)·H(2)O}(n), the Nd(III) atom is nine-coordinated by four O atoms from four pyridinium-4-carboxyl­ate ligands, two O atoms from a chelating nitrate anion and three water mol­ecules in a distorted tricapped trigonal–prismatic coordination geometry. Adjacent Nd atoms are linked by the bidentate pyridinium-4-carboxyl­ate ligands into a chain running along the b axis. The chains are further connected by O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968357/ /pubmed/21581760 http://dx.doi.org/10.1107/S1600536808043997 Text en © Jia-Zhi Pu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pu, Jia-Zhi
catena-Poly[[[triaqua­(nitrato-κ(2) O,O′)neodymium(III)]-bis­(μ(2)-pyridinium-4-carboxyl­ato-κ(2) O:O′)] bis­(perchlorate) monohydrate]
title catena-Poly[[[triaqua­(nitrato-κ(2) O,O′)neodymium(III)]-bis­(μ(2)-pyridinium-4-carboxyl­ato-κ(2) O:O′)] bis­(perchlorate) monohydrate]
title_full catena-Poly[[[triaqua­(nitrato-κ(2) O,O′)neodymium(III)]-bis­(μ(2)-pyridinium-4-carboxyl­ato-κ(2) O:O′)] bis­(perchlorate) monohydrate]
title_fullStr catena-Poly[[[triaqua­(nitrato-κ(2) O,O′)neodymium(III)]-bis­(μ(2)-pyridinium-4-carboxyl­ato-κ(2) O:O′)] bis­(perchlorate) monohydrate]
title_full_unstemmed catena-Poly[[[triaqua­(nitrato-κ(2) O,O′)neodymium(III)]-bis­(μ(2)-pyridinium-4-carboxyl­ato-κ(2) O:O′)] bis­(perchlorate) monohydrate]
title_short catena-Poly[[[triaqua­(nitrato-κ(2) O,O′)neodymium(III)]-bis­(μ(2)-pyridinium-4-carboxyl­ato-κ(2) O:O′)] bis­(perchlorate) monohydrate]
title_sort catena-poly[[[triaqua­(nitrato-κ(2) o,o′)neodymium(iii)]-bis­(μ(2)-pyridinium-4-carboxyl­ato-κ(2) o:o′)] bis­(perchlorate) monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968357/
https://www.ncbi.nlm.nih.gov/pubmed/21581760
http://dx.doi.org/10.1107/S1600536808043997
work_keys_str_mv AT pujiazhi catenapolytriaquanitratok2ooneodymiumiiibism2pyridinium4carboxylatok2oobisperchloratemonohydrate

Ejemplares similares