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4-(2-Iodo­benzene­sulfonamido)benzoic acid monohydrate

In the mol­ecule of the title compound, C(13)H(10)INO(4)S·H(2)O, the coordination around the S atom is distorted tetra­hedral. The aromatic rings are oriented at a dihedral angle of 74.18 (17)°. Intra­molecular C—H⋯O hydrogen bonds result in the formation of non-planar five- and six-membered rings,...

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Autores principales: Arshad, Muhammad Nadeem, Tahir, M. Nawaz, Khan, Islam Ullah, Siddiqui, Waseeq Ahmad, Shafiq, Muhammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968366/
https://www.ncbi.nlm.nih.gov/pubmed/21581847
http://dx.doi.org/10.1107/S1600536808043754
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author Arshad, Muhammad Nadeem
Tahir, M. Nawaz
Khan, Islam Ullah
Siddiqui, Waseeq Ahmad
Shafiq, Muhammad
author_facet Arshad, Muhammad Nadeem
Tahir, M. Nawaz
Khan, Islam Ullah
Siddiqui, Waseeq Ahmad
Shafiq, Muhammad
author_sort Arshad, Muhammad Nadeem
collection PubMed
description In the mol­ecule of the title compound, C(13)H(10)INO(4)S·H(2)O, the coordination around the S atom is distorted tetra­hedral. The aromatic rings are oriented at a dihedral angle of 74.18 (17)°. Intra­molecular C—H⋯O hydrogen bonds result in the formation of non-planar five- and six-membered rings, which adopt envelope and twist conformations, respectively. In the crystal structure, inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules. π–π Contacts between the phenyl rings [centroid–centroid distance = 3.726 (3) Å] may further stabilize the structure. There is also a C—H⋯π inter­action.
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spelling pubmed-29683662010-12-30 4-(2-Iodo­benzene­sulfonamido)benzoic acid monohydrate Arshad, Muhammad Nadeem Tahir, M. Nawaz Khan, Islam Ullah Siddiqui, Waseeq Ahmad Shafiq, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(13)H(10)INO(4)S·H(2)O, the coordination around the S atom is distorted tetra­hedral. The aromatic rings are oriented at a dihedral angle of 74.18 (17)°. Intra­molecular C—H⋯O hydrogen bonds result in the formation of non-planar five- and six-membered rings, which adopt envelope and twist conformations, respectively. In the crystal structure, inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules. π–π Contacts between the phenyl rings [centroid–centroid distance = 3.726 (3) Å] may further stabilize the structure. There is also a C—H⋯π inter­action. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968366/ /pubmed/21581847 http://dx.doi.org/10.1107/S1600536808043754 Text en © Arshad et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arshad, Muhammad Nadeem
Tahir, M. Nawaz
Khan, Islam Ullah
Siddiqui, Waseeq Ahmad
Shafiq, Muhammad
4-(2-Iodo­benzene­sulfonamido)benzoic acid monohydrate
title 4-(2-Iodo­benzene­sulfonamido)benzoic acid monohydrate
title_full 4-(2-Iodo­benzene­sulfonamido)benzoic acid monohydrate
title_fullStr 4-(2-Iodo­benzene­sulfonamido)benzoic acid monohydrate
title_full_unstemmed 4-(2-Iodo­benzene­sulfonamido)benzoic acid monohydrate
title_short 4-(2-Iodo­benzene­sulfonamido)benzoic acid monohydrate
title_sort 4-(2-iodo­benzene­sulfonamido)benzoic acid monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968366/
https://www.ncbi.nlm.nih.gov/pubmed/21581847
http://dx.doi.org/10.1107/S1600536808043754
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