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4-(2-Iodobenzenesulfonamido)benzoic acid monohydrate
In the molecule of the title compound, C(13)H(10)INO(4)S·H(2)O, the coordination around the S atom is distorted tetrahedral. The aromatic rings are oriented at a dihedral angle of 74.18 (17)°. Intramolecular C—H⋯O hydrogen bonds result in the formation of non-planar five- and six-membered rings,...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968366/ https://www.ncbi.nlm.nih.gov/pubmed/21581847 http://dx.doi.org/10.1107/S1600536808043754 |
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author | Arshad, Muhammad Nadeem Tahir, M. Nawaz Khan, Islam Ullah Siddiqui, Waseeq Ahmad Shafiq, Muhammad |
author_facet | Arshad, Muhammad Nadeem Tahir, M. Nawaz Khan, Islam Ullah Siddiqui, Waseeq Ahmad Shafiq, Muhammad |
author_sort | Arshad, Muhammad Nadeem |
collection | PubMed |
description | In the molecule of the title compound, C(13)H(10)INO(4)S·H(2)O, the coordination around the S atom is distorted tetrahedral. The aromatic rings are oriented at a dihedral angle of 74.18 (17)°. Intramolecular C—H⋯O hydrogen bonds result in the formation of non-planar five- and six-membered rings, which adopt envelope and twist conformations, respectively. In the crystal structure, intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the molecules. π–π Contacts between the phenyl rings [centroid–centroid distance = 3.726 (3) Å] may further stabilize the structure. There is also a C—H⋯π interaction. |
format | Text |
id | pubmed-2968366 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683662010-12-30 4-(2-Iodobenzenesulfonamido)benzoic acid monohydrate Arshad, Muhammad Nadeem Tahir, M. Nawaz Khan, Islam Ullah Siddiqui, Waseeq Ahmad Shafiq, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(13)H(10)INO(4)S·H(2)O, the coordination around the S atom is distorted tetrahedral. The aromatic rings are oriented at a dihedral angle of 74.18 (17)°. Intramolecular C—H⋯O hydrogen bonds result in the formation of non-planar five- and six-membered rings, which adopt envelope and twist conformations, respectively. In the crystal structure, intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the molecules. π–π Contacts between the phenyl rings [centroid–centroid distance = 3.726 (3) Å] may further stabilize the structure. There is also a C—H⋯π interaction. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968366/ /pubmed/21581847 http://dx.doi.org/10.1107/S1600536808043754 Text en © Arshad et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arshad, Muhammad Nadeem Tahir, M. Nawaz Khan, Islam Ullah Siddiqui, Waseeq Ahmad Shafiq, Muhammad 4-(2-Iodobenzenesulfonamido)benzoic acid monohydrate |
title | 4-(2-Iodobenzenesulfonamido)benzoic acid monohydrate |
title_full | 4-(2-Iodobenzenesulfonamido)benzoic acid monohydrate |
title_fullStr | 4-(2-Iodobenzenesulfonamido)benzoic acid monohydrate |
title_full_unstemmed | 4-(2-Iodobenzenesulfonamido)benzoic acid monohydrate |
title_short | 4-(2-Iodobenzenesulfonamido)benzoic acid monohydrate |
title_sort | 4-(2-iodobenzenesulfonamido)benzoic acid monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968366/ https://www.ncbi.nlm.nih.gov/pubmed/21581847 http://dx.doi.org/10.1107/S1600536808043754 |
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