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2-Benzoyl-1,1-diethyl-3-phenylguanidine
In the title tetrasubstituted guanidine, C(18)H(21)N(3)O, the guanidine and carbonyl groups are not coplanar, as reflected by the torsion angles involving the N=C atoms [17.6 (3), −141.68 (17) and 42.2 (3)°]. This is probably due to the absence of an intramolecular N—H⋯O hydrogen bond, forming a si...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968374/ https://www.ncbi.nlm.nih.gov/pubmed/21581944 http://dx.doi.org/10.1107/S1600536809001469 |
Sumario: | In the title tetrasubstituted guanidine, C(18)H(21)N(3)O, the guanidine and carbonyl groups are not coplanar, as reflected by the torsion angles involving the N=C atoms [17.6 (3), −141.68 (17) and 42.2 (3)°]. This is probably due to the absence of an intramolecular N—H⋯O hydrogen bond, forming a six-membered ring, and is commonly observed in this class of compounds. In the crystal structure, centrosymmetric dimers are formed via pairs of intermolecular N—H⋯O hydrogen bonds. The dihedral angles between the guanidine plane and the phenyl ring and benzoyl plane are38.06 (9) and 41.54 (7)°, respectively. |
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