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2-Benzoyl-1,1-diethyl-3-phenylguanidine
In the title tetrasubstituted guanidine, C(18)H(21)N(3)O, the guanidine and carbonyl groups are not coplanar, as reflected by the torsion angles involving the N=C atoms [17.6 (3), −141.68 (17) and 42.2 (3)°]. This is probably due to the absence of an intramolecular N—H⋯O hydrogen bond, forming a si...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968374/ https://www.ncbi.nlm.nih.gov/pubmed/21581944 http://dx.doi.org/10.1107/S1600536809001469 |
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author | Murtaza, Ghulam Hanif-Ur-Rehman, Khawar Rauf, M. Ebihara, Masahiro Badshah, Amin |
author_facet | Murtaza, Ghulam Hanif-Ur-Rehman, Khawar Rauf, M. Ebihara, Masahiro Badshah, Amin |
author_sort | Murtaza, Ghulam |
collection | PubMed |
description | In the title tetrasubstituted guanidine, C(18)H(21)N(3)O, the guanidine and carbonyl groups are not coplanar, as reflected by the torsion angles involving the N=C atoms [17.6 (3), −141.68 (17) and 42.2 (3)°]. This is probably due to the absence of an intramolecular N—H⋯O hydrogen bond, forming a six-membered ring, and is commonly observed in this class of compounds. In the crystal structure, centrosymmetric dimers are formed via pairs of intermolecular N—H⋯O hydrogen bonds. The dihedral angles between the guanidine plane and the phenyl ring and benzoyl plane are38.06 (9) and 41.54 (7)°, respectively. |
format | Text |
id | pubmed-2968374 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683742010-12-30 2-Benzoyl-1,1-diethyl-3-phenylguanidine Murtaza, Ghulam Hanif-Ur-Rehman, Khawar Rauf, M. Ebihara, Masahiro Badshah, Amin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title tetrasubstituted guanidine, C(18)H(21)N(3)O, the guanidine and carbonyl groups are not coplanar, as reflected by the torsion angles involving the N=C atoms [17.6 (3), −141.68 (17) and 42.2 (3)°]. This is probably due to the absence of an intramolecular N—H⋯O hydrogen bond, forming a six-membered ring, and is commonly observed in this class of compounds. In the crystal structure, centrosymmetric dimers are formed via pairs of intermolecular N—H⋯O hydrogen bonds. The dihedral angles between the guanidine plane and the phenyl ring and benzoyl plane are38.06 (9) and 41.54 (7)°, respectively. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968374/ /pubmed/21581944 http://dx.doi.org/10.1107/S1600536809001469 Text en © Murtaza et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Murtaza, Ghulam Hanif-Ur-Rehman, Khawar Rauf, M. Ebihara, Masahiro Badshah, Amin 2-Benzoyl-1,1-diethyl-3-phenylguanidine |
title | 2-Benzoyl-1,1-diethyl-3-phenylguanidine |
title_full | 2-Benzoyl-1,1-diethyl-3-phenylguanidine |
title_fullStr | 2-Benzoyl-1,1-diethyl-3-phenylguanidine |
title_full_unstemmed | 2-Benzoyl-1,1-diethyl-3-phenylguanidine |
title_short | 2-Benzoyl-1,1-diethyl-3-phenylguanidine |
title_sort | 2-benzoyl-1,1-diethyl-3-phenylguanidine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968374/ https://www.ncbi.nlm.nih.gov/pubmed/21581944 http://dx.doi.org/10.1107/S1600536809001469 |
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