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2-Benzoyl-1,1-diethyl-3-phenyl­guanidine

In the title tetrasubstituted guanidine, C(18)H(21)N(3)O, the guanidine and carbonyl groups are not coplanar, as reflected by the torsion angles involving the N=C atoms [17.6 (3), −141.68 (17) and 42.2 (3)°]. This is probably due to the absence of an intra­molecular N—H⋯O hydrogen bond, forming a si...

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Detalles Bibliográficos
Autores principales: Murtaza, Ghulam, Hanif-Ur-Rehman, Khawar Rauf, M., Ebihara, Masahiro, Badshah, Amin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968374/
https://www.ncbi.nlm.nih.gov/pubmed/21581944
http://dx.doi.org/10.1107/S1600536809001469
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author Murtaza, Ghulam
Hanif-Ur-Rehman,
Khawar Rauf, M.
Ebihara, Masahiro
Badshah, Amin
author_facet Murtaza, Ghulam
Hanif-Ur-Rehman,
Khawar Rauf, M.
Ebihara, Masahiro
Badshah, Amin
author_sort Murtaza, Ghulam
collection PubMed
description In the title tetrasubstituted guanidine, C(18)H(21)N(3)O, the guanidine and carbonyl groups are not coplanar, as reflected by the torsion angles involving the N=C atoms [17.6 (3), −141.68 (17) and 42.2 (3)°]. This is probably due to the absence of an intra­molecular N—H⋯O hydrogen bond, forming a six-membered ring, and is commonly observed in this class of compounds. In the crystal structure, centrosymmetric dimers are formed via pairs of inter­molecular N—H⋯O hydrogen bonds. The dihedral angles between the guanidine plane and the phenyl ring and benzoyl plane are38.06 (9) and 41.54 (7)°, respectively.
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spelling pubmed-29683742010-12-30 2-Benzoyl-1,1-diethyl-3-phenyl­guanidine Murtaza, Ghulam Hanif-Ur-Rehman, Khawar Rauf, M. Ebihara, Masahiro Badshah, Amin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title tetrasubstituted guanidine, C(18)H(21)N(3)O, the guanidine and carbonyl groups are not coplanar, as reflected by the torsion angles involving the N=C atoms [17.6 (3), −141.68 (17) and 42.2 (3)°]. This is probably due to the absence of an intra­molecular N—H⋯O hydrogen bond, forming a six-membered ring, and is commonly observed in this class of compounds. In the crystal structure, centrosymmetric dimers are formed via pairs of inter­molecular N—H⋯O hydrogen bonds. The dihedral angles between the guanidine plane and the phenyl ring and benzoyl plane are38.06 (9) and 41.54 (7)°, respectively. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968374/ /pubmed/21581944 http://dx.doi.org/10.1107/S1600536809001469 Text en © Murtaza et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Murtaza, Ghulam
Hanif-Ur-Rehman,
Khawar Rauf, M.
Ebihara, Masahiro
Badshah, Amin
2-Benzoyl-1,1-diethyl-3-phenyl­guanidine
title 2-Benzoyl-1,1-diethyl-3-phenyl­guanidine
title_full 2-Benzoyl-1,1-diethyl-3-phenyl­guanidine
title_fullStr 2-Benzoyl-1,1-diethyl-3-phenyl­guanidine
title_full_unstemmed 2-Benzoyl-1,1-diethyl-3-phenyl­guanidine
title_short 2-Benzoyl-1,1-diethyl-3-phenyl­guanidine
title_sort 2-benzoyl-1,1-diethyl-3-phenyl­guanidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968374/
https://www.ncbi.nlm.nih.gov/pubmed/21581944
http://dx.doi.org/10.1107/S1600536809001469
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