N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide

In the title compound, C(24)H(12)BrF(2)NO(4), synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 4-fluoro­benzoyl chloride, the two p-fluoro­phenyl rings are inclined at 73.9 (1) and 73.6 (1)° to the naphthoquinone ring system. The two imido carbonyl O atoms are anti to each other, while the fl...

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Autores principales: Akinboye, Emmanuel S., Butcher, Ray J., Wright, Dwayne A., Brandy, Yakini, Bakare, Oladapo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968378/
https://www.ncbi.nlm.nih.gov/pubmed/21581890
http://dx.doi.org/10.1107/S1600536809000117
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author Akinboye, Emmanuel S.
Butcher, Ray J.
Wright, Dwayne A.
Brandy, Yakini
Bakare, Oladapo
author_facet Akinboye, Emmanuel S.
Butcher, Ray J.
Wright, Dwayne A.
Brandy, Yakini
Bakare, Oladapo
author_sort Akinboye, Emmanuel S.
collection PubMed
description In the title compound, C(24)H(12)BrF(2)NO(4), synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 4-fluoro­benzoyl chloride, the two p-fluoro­phenyl rings are inclined at 73.9 (1) and 73.6 (1)° to the naphthoquinone ring system. The two imido carbonyl O atoms are anti to each other, while the fluoro­phenyl rings are located opposite each other, connected to the imide group in a funnel-like arrangement. This conformation allows the fluorine groups be oriented slightly away from each other. An examination of the packing shows a close inter­molecular F⋯O contact of 2.982 (5) Å and a Br⋯O contact of 2.977 (4) Å. In addition, the mol­ecules are linked by weak inter­molecular C—H⋯O and C—H⋯F inter­actions.
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spelling pubmed-29683782010-12-30 N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide Akinboye, Emmanuel S. Butcher, Ray J. Wright, Dwayne A. Brandy, Yakini Bakare, Oladapo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(12)BrF(2)NO(4), synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 4-fluoro­benzoyl chloride, the two p-fluoro­phenyl rings are inclined at 73.9 (1) and 73.6 (1)° to the naphthoquinone ring system. The two imido carbonyl O atoms are anti to each other, while the fluoro­phenyl rings are located opposite each other, connected to the imide group in a funnel-like arrangement. This conformation allows the fluorine groups be oriented slightly away from each other. An examination of the packing shows a close inter­molecular F⋯O contact of 2.982 (5) Å and a Br⋯O contact of 2.977 (4) Å. In addition, the mol­ecules are linked by weak inter­molecular C—H⋯O and C—H⋯F inter­actions. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968378/ /pubmed/21581890 http://dx.doi.org/10.1107/S1600536809000117 Text en © Akinboye et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akinboye, Emmanuel S.
Butcher, Ray J.
Wright, Dwayne A.
Brandy, Yakini
Bakare, Oladapo
N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide
title N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide
title_full N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide
title_fullStr N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide
title_full_unstemmed N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide
title_short N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide
title_sort n-(3-bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-n-(4-fluoro­benzo­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968378/
https://www.ncbi.nlm.nih.gov/pubmed/21581890
http://dx.doi.org/10.1107/S1600536809000117
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AT brandyyakini n3bromo14dioxo14dihydro2naphthyl4fluoron4fluorobenzoylbenzamide
AT bakareoladapo n3bromo14dioxo14dihydro2naphthyl4fluoron4fluorobenzoylbenzamide

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