(2Z)-Ethyl 5-(4-methoxy­phen­yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy­benzyl­idene)-3,5-dihydro-2H-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate

In the title compound, C(27)H(28)N(2)O(7)S, the dihedral angles between the thia­zole ring and the mono- and tris­ubstituted benzene rings are 87.8 (2) and 17.9 (3)°, respectively. The dihydro­pyrimidine ring adopts a flattened boat conformation. In the crystal structure, π–π stacking occurs [centro...

Descripción completa

Detalles Bibliográficos
Autor principal: Hou, Zhao-Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968379/
https://www.ncbi.nlm.nih.gov/pubmed/21581852
http://dx.doi.org/10.1107/S1600536808041019
_version_ 1782189857883291648
author Hou, Zhao-Hui
author_facet Hou, Zhao-Hui
author_sort Hou, Zhao-Hui
collection PubMed
description In the title compound, C(27)H(28)N(2)O(7)S, the dihedral angles between the thia­zole ring and the mono- and tris­ubstituted benzene rings are 87.8 (2) and 17.9 (3)°, respectively. The dihydro­pyrimidine ring adopts a flattened boat conformation. In the crystal structure, π–π stacking occurs [centroid–centroid separation = 3.6611 (11) Å].
format Text
id pubmed-2968379
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29683792010-12-30 (2Z)-Ethyl 5-(4-methoxy­phen­yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy­benzyl­idene)-3,5-dihydro-2H-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate Hou, Zhao-Hui Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(28)N(2)O(7)S, the dihedral angles between the thia­zole ring and the mono- and tris­ubstituted benzene rings are 87.8 (2) and 17.9 (3)°, respectively. The dihydro­pyrimidine ring adopts a flattened boat conformation. In the crystal structure, π–π stacking occurs [centroid–centroid separation = 3.6611 (11) Å]. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968379/ /pubmed/21581852 http://dx.doi.org/10.1107/S1600536808041019 Text en © Zhao-Hui Hou 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hou, Zhao-Hui
(2Z)-Ethyl 5-(4-methoxy­phen­yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy­benzyl­idene)-3,5-dihydro-2H-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title (2Z)-Ethyl 5-(4-methoxy­phen­yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy­benzyl­idene)-3,5-dihydro-2H-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_full (2Z)-Ethyl 5-(4-methoxy­phen­yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy­benzyl­idene)-3,5-dihydro-2H-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_fullStr (2Z)-Ethyl 5-(4-methoxy­phen­yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy­benzyl­idene)-3,5-dihydro-2H-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_full_unstemmed (2Z)-Ethyl 5-(4-methoxy­phen­yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy­benzyl­idene)-3,5-dihydro-2H-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_short (2Z)-Ethyl 5-(4-methoxy­phen­yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy­benzyl­idene)-3,5-dihydro-2H-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_sort (2z)-ethyl 5-(4-methoxy­phen­yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy­benzyl­idene)-3,5-dihydro-2h-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968379/
https://www.ncbi.nlm.nih.gov/pubmed/21581852
http://dx.doi.org/10.1107/S1600536808041019
work_keys_str_mv AT houzhaohui 2zethyl54methoxyphenyl7methyl3oxo2345trimethoxybenzylidene35dihydro2hthiazolo32apyrimidine6carboxylate

Ejemplares similares