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Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate
In the title compound, 0.5C(10)H(10)N(2) (2+)·PF(6) (−)·C(10)H(8)N(2)·2C(7)H(7)NO(2)·H(2)O, the cation is located on a center of symmetry. The crystal structure is determined by a complex three-dimensional network of intermolecular O—H⋯O, O—H⋯N, N—H⋯N and N—H⋯F hydrogen bonds. π–π stacking interac...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968380/ https://www.ncbi.nlm.nih.gov/pubmed/21581891 http://dx.doi.org/10.1107/S1600536808043900 |
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author | Wu, Yi-Yi Huang, Chun-De Huang, Jie-Xuan Zeng, Rong-Hua Luo, Yi-Fan |
author_facet | Wu, Yi-Yi Huang, Chun-De Huang, Jie-Xuan Zeng, Rong-Hua Luo, Yi-Fan |
author_sort | Wu, Yi-Yi |
collection | PubMed |
description | In the title compound, 0.5C(10)H(10)N(2) (2+)·PF(6) (−)·C(10)H(8)N(2)·2C(7)H(7)NO(2)·H(2)O, the cation is located on a center of symmetry. The crystal structure is determined by a complex three-dimensional network of intermolecular O—H⋯O, O—H⋯N, N—H⋯N and N—H⋯F hydrogen bonds. π–π stacking interactions between neighboring pyridyl rings are also present; the centroid–centroid distance is 3.643 (5) Å. The hexafluoridophosphate anion is disordered over two positions with site-occupancy factors of ca 0.6 and 0.4. |
format | Text |
id | pubmed-2968380 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683802010-12-30 Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate Wu, Yi-Yi Huang, Chun-De Huang, Jie-Xuan Zeng, Rong-Hua Luo, Yi-Fan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, 0.5C(10)H(10)N(2) (2+)·PF(6) (−)·C(10)H(8)N(2)·2C(7)H(7)NO(2)·H(2)O, the cation is located on a center of symmetry. The crystal structure is determined by a complex three-dimensional network of intermolecular O—H⋯O, O—H⋯N, N—H⋯N and N—H⋯F hydrogen bonds. π–π stacking interactions between neighboring pyridyl rings are also present; the centroid–centroid distance is 3.643 (5) Å. The hexafluoridophosphate anion is disordered over two positions with site-occupancy factors of ca 0.6 and 0.4. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968380/ /pubmed/21581891 http://dx.doi.org/10.1107/S1600536808043900 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wu, Yi-Yi Huang, Chun-De Huang, Jie-Xuan Zeng, Rong-Hua Luo, Yi-Fan Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
title | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
title_full | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
title_fullStr | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
title_full_unstemmed | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
title_short | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
title_sort | hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968380/ https://www.ncbi.nlm.nih.gov/pubmed/21581891 http://dx.doi.org/10.1107/S1600536808043900 |
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