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Aqua­bis(2-iodo­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title compound, [Cu(C(2)H(2)IO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated by two N atoms [Cu—N = 2.013 (4) and 2.024 (4) Å] from a 1,10-phenanthroline ligand and three O atoms [Cu—O = 1.940 (4)–2.261 (4) Å] from two carboxyl ligands and a water mol­ecule in a distorted squar...

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Detalles Bibliográficos
Autores principales: Zhao, Rengao, Sun, Junshan, Lu, Jie, Li, Jikun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968381/
https://www.ncbi.nlm.nih.gov/pubmed/21581830
http://dx.doi.org/10.1107/S1600536809002682
Descripción
Sumario:In the title compound, [Cu(C(2)H(2)IO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated by two N atoms [Cu—N = 2.013 (4) and 2.024 (4) Å] from a 1,10-phenanthroline ligand and three O atoms [Cu—O = 1.940 (4)–2.261 (4) Å] from two carboxyl ligands and a water mol­ecule in a distorted square-pyramidal geometry. One iodo­acetate O atom [Cu—O = 2.775 (4) Å] completes the coordination to form a distorted octa­hedron. Inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers, which are further packed by π–π inter­actions between the 1,10-phenanthroline ligands into layers parallel to the ab plane. The crystal packing also exhibits short inter­molecular I⋯I contacts of 3.6772 (9) Å and weak C—H⋯O hydrogen bonds.