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Aqua­bis(2-iodo­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title compound, [Cu(C(2)H(2)IO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated by two N atoms [Cu—N = 2.013 (4) and 2.024 (4) Å] from a 1,10-phenanthroline ligand and three O atoms [Cu—O = 1.940 (4)–2.261 (4) Å] from two carboxyl ligands and a water mol­ecule in a distorted squar...

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Detalles Bibliográficos
Autores principales: Zhao, Rengao, Sun, Junshan, Lu, Jie, Li, Jikun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968381/
https://www.ncbi.nlm.nih.gov/pubmed/21581830
http://dx.doi.org/10.1107/S1600536809002682
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author Zhao, Rengao
Sun, Junshan
Lu, Jie
Li, Jikun
author_facet Zhao, Rengao
Sun, Junshan
Lu, Jie
Li, Jikun
author_sort Zhao, Rengao
collection PubMed
description In the title compound, [Cu(C(2)H(2)IO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated by two N atoms [Cu—N = 2.013 (4) and 2.024 (4) Å] from a 1,10-phenanthroline ligand and three O atoms [Cu—O = 1.940 (4)–2.261 (4) Å] from two carboxyl ligands and a water mol­ecule in a distorted square-pyramidal geometry. One iodo­acetate O atom [Cu—O = 2.775 (4) Å] completes the coordination to form a distorted octa­hedron. Inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers, which are further packed by π–π inter­actions between the 1,10-phenanthroline ligands into layers parallel to the ab plane. The crystal packing also exhibits short inter­molecular I⋯I contacts of 3.6772 (9) Å and weak C—H⋯O hydrogen bonds.
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spelling pubmed-29683812010-12-30 Aqua­bis(2-iodo­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Zhao, Rengao Sun, Junshan Lu, Jie Li, Jikun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(2)IO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated by two N atoms [Cu—N = 2.013 (4) and 2.024 (4) Å] from a 1,10-phenanthroline ligand and three O atoms [Cu—O = 1.940 (4)–2.261 (4) Å] from two carboxyl ligands and a water mol­ecule in a distorted square-pyramidal geometry. One iodo­acetate O atom [Cu—O = 2.775 (4) Å] completes the coordination to form a distorted octa­hedron. Inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers, which are further packed by π–π inter­actions between the 1,10-phenanthroline ligands into layers parallel to the ab plane. The crystal packing also exhibits short inter­molecular I⋯I contacts of 3.6772 (9) Å and weak C—H⋯O hydrogen bonds. International Union of Crystallography 2009-01-31 /pmc/articles/PMC2968381/ /pubmed/21581830 http://dx.doi.org/10.1107/S1600536809002682 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Rengao
Sun, Junshan
Lu, Jie
Li, Jikun
Aqua­bis(2-iodo­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title Aqua­bis(2-iodo­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Aqua­bis(2-iodo­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Aqua­bis(2-iodo­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Aqua­bis(2-iodo­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Aqua­bis(2-iodo­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort aqua­bis(2-iodo­acetato-κo)(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968381/
https://www.ncbi.nlm.nih.gov/pubmed/21581830
http://dx.doi.org/10.1107/S1600536809002682
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