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Aquabis(2-iodoacetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
In the title compound, [Cu(C(2)H(2)IO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated by two N atoms [Cu—N = 2.013 (4) and 2.024 (4) Å] from a 1,10-phenanthroline ligand and three O atoms [Cu—O = 1.940 (4)–2.261 (4) Å] from two carboxyl ligands and a water molecule in a distorted squar...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968381/ https://www.ncbi.nlm.nih.gov/pubmed/21581830 http://dx.doi.org/10.1107/S1600536809002682 |
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author | Zhao, Rengao Sun, Junshan Lu, Jie Li, Jikun |
author_facet | Zhao, Rengao Sun, Junshan Lu, Jie Li, Jikun |
author_sort | Zhao, Rengao |
collection | PubMed |
description | In the title compound, [Cu(C(2)H(2)IO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated by two N atoms [Cu—N = 2.013 (4) and 2.024 (4) Å] from a 1,10-phenanthroline ligand and three O atoms [Cu—O = 1.940 (4)–2.261 (4) Å] from two carboxyl ligands and a water molecule in a distorted square-pyramidal geometry. One iodoacetate O atom [Cu—O = 2.775 (4) Å] completes the coordination to form a distorted octahedron. Intermolecular O—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers, which are further packed by π–π interactions between the 1,10-phenanthroline ligands into layers parallel to the ab plane. The crystal packing also exhibits short intermolecular I⋯I contacts of 3.6772 (9) Å and weak C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2968381 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683812010-12-30 Aquabis(2-iodoacetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Zhao, Rengao Sun, Junshan Lu, Jie Li, Jikun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(2)IO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated by two N atoms [Cu—N = 2.013 (4) and 2.024 (4) Å] from a 1,10-phenanthroline ligand and three O atoms [Cu—O = 1.940 (4)–2.261 (4) Å] from two carboxyl ligands and a water molecule in a distorted square-pyramidal geometry. One iodoacetate O atom [Cu—O = 2.775 (4) Å] completes the coordination to form a distorted octahedron. Intermolecular O—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers, which are further packed by π–π interactions between the 1,10-phenanthroline ligands into layers parallel to the ab plane. The crystal packing also exhibits short intermolecular I⋯I contacts of 3.6772 (9) Å and weak C—H⋯O hydrogen bonds. International Union of Crystallography 2009-01-31 /pmc/articles/PMC2968381/ /pubmed/21581830 http://dx.doi.org/10.1107/S1600536809002682 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Rengao Sun, Junshan Lu, Jie Li, Jikun Aquabis(2-iodoacetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) |
title | Aquabis(2-iodoacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full | Aquabis(2-iodoacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_fullStr | Aquabis(2-iodoacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full_unstemmed | Aquabis(2-iodoacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_short | Aquabis(2-iodoacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_sort | aquabis(2-iodoacetato-κo)(1,10-phenanthroline-κ(2)
n,n′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968381/ https://www.ncbi.nlm.nih.gov/pubmed/21581830 http://dx.doi.org/10.1107/S1600536809002682 |
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