Di-μ-chlorido-bis­{aqua­chlorido[3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]manganese(II)}

In the centrosymmetric dinuclear title compound, [Mn(2)Cl(4)(C(15)H(14)N(4))(2)(H(2)O)(2)], the Mn(II) atom is coordinated by an N,N′-bidentate ligand, a water mol­ecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN(2)OCl(3) octa­hedral geometry. The Mn⋯Mn separation is...

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Detalles Bibliográficos
Autores principales: Wang, Zuoxiang, Gong, Ixaoning, Liu, Chunyi, Zhang, Xiaoming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968385/
https://www.ncbi.nlm.nih.gov/pubmed/21581769
http://dx.doi.org/10.1107/S1600536808044103
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author Wang, Zuoxiang
Gong, Ixaoning
Liu, Chunyi
Zhang, Xiaoming
author_facet Wang, Zuoxiang
Gong, Ixaoning
Liu, Chunyi
Zhang, Xiaoming
author_sort Wang, Zuoxiang
collection PubMed
description In the centrosymmetric dinuclear title compound, [Mn(2)Cl(4)(C(15)H(14)N(4))(2)(H(2)O)(2)], the Mn(II) atom is coordinated by an N,N′-bidentate ligand, a water mol­ecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN(2)OCl(3) octa­hedral geometry. The Mn⋯Mn separation is 3.6563 (9) Å. In the crystal structure, O—H⋯N and O—H⋯Cl hydrogen bonds help to establish the packing.
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spelling pubmed-29683852010-12-30 Di-μ-chlorido-bis­{aqua­chlorido[3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]manganese(II)} Wang, Zuoxiang Gong, Ixaoning Liu, Chunyi Zhang, Xiaoming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Mn(2)Cl(4)(C(15)H(14)N(4))(2)(H(2)O)(2)], the Mn(II) atom is coordinated by an N,N′-bidentate ligand, a water mol­ecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN(2)OCl(3) octa­hedral geometry. The Mn⋯Mn separation is 3.6563 (9) Å. In the crystal structure, O—H⋯N and O—H⋯Cl hydrogen bonds help to establish the packing. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968385/ /pubmed/21581769 http://dx.doi.org/10.1107/S1600536808044103 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zuoxiang
Gong, Ixaoning
Liu, Chunyi
Zhang, Xiaoming
Di-μ-chlorido-bis­{aqua­chlorido[3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]manganese(II)}
title Di-μ-chlorido-bis­{aqua­chlorido[3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]manganese(II)}
title_full Di-μ-chlorido-bis­{aqua­chlorido[3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]manganese(II)}
title_fullStr Di-μ-chlorido-bis­{aqua­chlorido[3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]manganese(II)}
title_full_unstemmed Di-μ-chlorido-bis­{aqua­chlorido[3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]manganese(II)}
title_short Di-μ-chlorido-bis­{aqua­chlorido[3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]manganese(II)}
title_sort di-μ-chlorido-bis­{aqua­chlorido[3-ethyl-4-phenyl-5-(2-pyrid­yl)-4h-1,2,4-triazole-κ(2) n (1),n (5)]manganese(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968385/
https://www.ncbi.nlm.nih.gov/pubmed/21581769
http://dx.doi.org/10.1107/S1600536808044103
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