Bis(μ-dimesitylborinato-κ(2) O:O)bis­[(2-methyl­pyridine-κN)lithium]

The title compound, [Li(2)(C(18)H(22)BO)(2)(C(6)H(7)N)(2)], is a lithium dimesitylboroxide dimer in which the lithium cation is also coordinated by one mol­ecule of 2-methyl­pyridine. At the core of the structure is an Li(2)O(2) four-membered ring. The structure is centrosymmetric with an inversion...

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Detalles Bibliográficos
Autores principales: Saravana, K. T. Pillai, Son, Jung-Ho, Hoefelmeyer, James D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968386/
https://www.ncbi.nlm.nih.gov/pubmed/21581783
http://dx.doi.org/10.1107/S1600536808042748
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author Saravana, K. T. Pillai
Son, Jung-Ho
Hoefelmeyer, James D.
author_facet Saravana, K. T. Pillai
Son, Jung-Ho
Hoefelmeyer, James D.
author_sort Saravana, K. T. Pillai
collection PubMed
description The title compound, [Li(2)(C(18)H(22)BO)(2)(C(6)H(7)N)(2)], is a lithium dimesitylboroxide dimer in which the lithium cation is also coordinated by one mol­ecule of 2-methyl­pyridine. At the core of the structure is an Li(2)O(2) four-membered ring. The structure is centrosymmetric with an inversion centre midway between two Li atoms. Inter­molecular C—H⋯π inter­actions and π–π inter­actions between the 2-methyl­pyridine rings exist [centroid–centroid distance = 3.6312 (16) Å].
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spelling pubmed-29683862010-12-30 Bis(μ-dimesitylborinato-κ(2) O:O)bis­[(2-methyl­pyridine-κN)lithium] Saravana, K. T. Pillai Son, Jung-Ho Hoefelmeyer, James D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Li(2)(C(18)H(22)BO)(2)(C(6)H(7)N)(2)], is a lithium dimesitylboroxide dimer in which the lithium cation is also coordinated by one mol­ecule of 2-methyl­pyridine. At the core of the structure is an Li(2)O(2) four-membered ring. The structure is centrosymmetric with an inversion centre midway between two Li atoms. Inter­molecular C—H⋯π inter­actions and π–π inter­actions between the 2-methyl­pyridine rings exist [centroid–centroid distance = 3.6312 (16) Å]. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968386/ /pubmed/21581783 http://dx.doi.org/10.1107/S1600536808042748 Text en © Saravana et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Saravana, K. T. Pillai
Son, Jung-Ho
Hoefelmeyer, James D.
Bis(μ-dimesitylborinato-κ(2) O:O)bis­[(2-methyl­pyridine-κN)lithium]
title Bis(μ-dimesitylborinato-κ(2) O:O)bis­[(2-methyl­pyridine-κN)lithium]
title_full Bis(μ-dimesitylborinato-κ(2) O:O)bis­[(2-methyl­pyridine-κN)lithium]
title_fullStr Bis(μ-dimesitylborinato-κ(2) O:O)bis­[(2-methyl­pyridine-κN)lithium]
title_full_unstemmed Bis(μ-dimesitylborinato-κ(2) O:O)bis­[(2-methyl­pyridine-κN)lithium]
title_short Bis(μ-dimesitylborinato-κ(2) O:O)bis­[(2-methyl­pyridine-κN)lithium]
title_sort bis(μ-dimesitylborinato-κ(2) o:o)bis­[(2-methyl­pyridine-κn)lithium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968386/
https://www.ncbi.nlm.nih.gov/pubmed/21581783
http://dx.doi.org/10.1107/S1600536808042748
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AT hoefelmeyerjamesd bismdimesitylborinatok2oobis2methylpyridineknlithium

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