(E)-4-Chloro-N-[(E)-2-methyl-3-phenyl­allyl­idene]aniline

The title Schiff base compound, C(16)H(14)ClN, adopts E configurations with respect to both the C=C and C=N bonds. The dihedral angle between the two aromatic rings is 53.27 (4)°, while the plane through the C=C—C=N system is inclined at 9.06 (8)° to the benzene ring and 44.92 (5)° to the chloro­ben...

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Detalles Bibliográficos
Autores principales: Khalaji, Aliakbar D., Simpson, Jim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968393/
https://www.ncbi.nlm.nih.gov/pubmed/21581960
http://dx.doi.org/10.1107/S1600536809001871
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author Khalaji, Aliakbar D.
Simpson, Jim
author_facet Khalaji, Aliakbar D.
Simpson, Jim
author_sort Khalaji, Aliakbar D.
collection PubMed
description The title Schiff base compound, C(16)H(14)ClN, adopts E configurations with respect to both the C=C and C=N bonds. The dihedral angle between the two aromatic rings is 53.27 (4)°, while the plane through the C=C—C=N system is inclined at 9.06 (8)° to the benzene ring and 44.92 (5)° to the chloro­benzene ring. In the crystal structure, weak C—H⋯Cl and C—H⋯N hydrogen bonds stack the mol­ecules down the a axis.
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spelling pubmed-29683932010-12-30 (E)-4-Chloro-N-[(E)-2-methyl-3-phenyl­allyl­idene]aniline Khalaji, Aliakbar D. Simpson, Jim Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(16)H(14)ClN, adopts E configurations with respect to both the C=C and C=N bonds. The dihedral angle between the two aromatic rings is 53.27 (4)°, while the plane through the C=C—C=N system is inclined at 9.06 (8)° to the benzene ring and 44.92 (5)° to the chloro­benzene ring. In the crystal structure, weak C—H⋯Cl and C—H⋯N hydrogen bonds stack the mol­ecules down the a axis. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968393/ /pubmed/21581960 http://dx.doi.org/10.1107/S1600536809001871 Text en © Khalaji and Simpson 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khalaji, Aliakbar D.
Simpson, Jim
(E)-4-Chloro-N-[(E)-2-methyl-3-phenyl­allyl­idene]aniline
title (E)-4-Chloro-N-[(E)-2-methyl-3-phenyl­allyl­idene]aniline
title_full (E)-4-Chloro-N-[(E)-2-methyl-3-phenyl­allyl­idene]aniline
title_fullStr (E)-4-Chloro-N-[(E)-2-methyl-3-phenyl­allyl­idene]aniline
title_full_unstemmed (E)-4-Chloro-N-[(E)-2-methyl-3-phenyl­allyl­idene]aniline
title_short (E)-4-Chloro-N-[(E)-2-methyl-3-phenyl­allyl­idene]aniline
title_sort (e)-4-chloro-n-[(e)-2-methyl-3-phenyl­allyl­idene]aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968393/
https://www.ncbi.nlm.nih.gov/pubmed/21581960
http://dx.doi.org/10.1107/S1600536809001871
work_keys_str_mv AT khalajialiakbard e4chlorone2methyl3phenylallylideneaniline
AT simpsonjim e4chlorone2methyl3phenylallylideneaniline

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