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2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid
In the molecule of the title compound, C(13)H(9)ClINO(4)S, the coordination around the S atom is distorted tetrahedral. The aromatic rings are oriented at a dihedral angle of 74.46 (9)°. Intramolecular C—H⋯O hydrogen bonds result in the formation of two five- and one six-membered rings, which ado...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968399/ https://www.ncbi.nlm.nih.gov/pubmed/21581894 http://dx.doi.org/10.1107/S1600536808043869 |
Sumario: | In the molecule of the title compound, C(13)H(9)ClINO(4)S, the coordination around the S atom is distorted tetrahedral. The aromatic rings are oriented at a dihedral angle of 74.46 (9)°. Intramolecular C—H⋯O hydrogen bonds result in the formation of two five- and one six-membered rings, which adopt planar, envelope and twisted conformations, respectively. In the crystal structure, intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the molecules to form R (2) (2)(8) ring motifs, which are further linked by C—H⋯O hydrogen bonds. π–π contacts between the benzene rings [centroid–centroid distances = 3.709 (3) and 3.772 (3) Å] may further stabilize the structure. The I atom is disordered over two positions, refined with occupancies of ca 0.75 and 0.25. |
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