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2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid
In the molecule of the title compound, C(13)H(9)ClINO(4)S, the coordination around the S atom is distorted tetrahedral. The aromatic rings are oriented at a dihedral angle of 74.46 (9)°. Intramolecular C—H⋯O hydrogen bonds result in the formation of two five- and one six-membered rings, which ado...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968399/ https://www.ncbi.nlm.nih.gov/pubmed/21581894 http://dx.doi.org/10.1107/S1600536808043869 |
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author | Arshad, Muhammad Nadeem Tahir, M. Nawaz Khan, Islam Ullah Siddiqui, Waseeq Ahmad Shafiq, Muhammad |
author_facet | Arshad, Muhammad Nadeem Tahir, M. Nawaz Khan, Islam Ullah Siddiqui, Waseeq Ahmad Shafiq, Muhammad |
author_sort | Arshad, Muhammad Nadeem |
collection | PubMed |
description | In the molecule of the title compound, C(13)H(9)ClINO(4)S, the coordination around the S atom is distorted tetrahedral. The aromatic rings are oriented at a dihedral angle of 74.46 (9)°. Intramolecular C—H⋯O hydrogen bonds result in the formation of two five- and one six-membered rings, which adopt planar, envelope and twisted conformations, respectively. In the crystal structure, intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the molecules to form R (2) (2)(8) ring motifs, which are further linked by C—H⋯O hydrogen bonds. π–π contacts between the benzene rings [centroid–centroid distances = 3.709 (3) and 3.772 (3) Å] may further stabilize the structure. The I atom is disordered over two positions, refined with occupancies of ca 0.75 and 0.25. |
format | Text |
id | pubmed-2968399 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683992010-12-30 2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid Arshad, Muhammad Nadeem Tahir, M. Nawaz Khan, Islam Ullah Siddiqui, Waseeq Ahmad Shafiq, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(13)H(9)ClINO(4)S, the coordination around the S atom is distorted tetrahedral. The aromatic rings are oriented at a dihedral angle of 74.46 (9)°. Intramolecular C—H⋯O hydrogen bonds result in the formation of two five- and one six-membered rings, which adopt planar, envelope and twisted conformations, respectively. In the crystal structure, intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the molecules to form R (2) (2)(8) ring motifs, which are further linked by C—H⋯O hydrogen bonds. π–π contacts between the benzene rings [centroid–centroid distances = 3.709 (3) and 3.772 (3) Å] may further stabilize the structure. The I atom is disordered over two positions, refined with occupancies of ca 0.75 and 0.25. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968399/ /pubmed/21581894 http://dx.doi.org/10.1107/S1600536808043869 Text en © Arshad et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arshad, Muhammad Nadeem Tahir, M. Nawaz Khan, Islam Ullah Siddiqui, Waseeq Ahmad Shafiq, Muhammad 2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid |
title | 2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid |
title_full | 2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid |
title_fullStr | 2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid |
title_full_unstemmed | 2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid |
title_short | 2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid |
title_sort | 2-chloro-5-(2-iodobenzenesulfonamido)benzoic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968399/ https://www.ncbi.nlm.nih.gov/pubmed/21581894 http://dx.doi.org/10.1107/S1600536808043869 |
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