Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphen­yl)carbamo­yl]-2,2′-bi­pyridine-4-carboxyl­ate}ruthenium(II) bis­[hexa­fluorido­phosphate(V)]

In the title compound, [Ru(C(10)H(8)N(2))(2)(C(21)H(18)N(4)O(4))](PF(6))(2), the Ru(II) complex cation reveals a slightly distorted octa­hedral coordination. The coordination bonds of the 4,4′-substituted bipyridyl donors [Ru—N = 2.038 (3) and 2.051 (3) Å] are shorter than those of the 2,2′-bipyridy...

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Detalles Bibliográficos
Autores principales: Hirahara, Masanari, Masaoka, Shigeyuki, Sakai, Ken
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968400/
https://www.ncbi.nlm.nih.gov/pubmed/21581819
http://dx.doi.org/10.1107/S1600536809002360
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author Hirahara, Masanari
Masaoka, Shigeyuki
Sakai, Ken
author_facet Hirahara, Masanari
Masaoka, Shigeyuki
Sakai, Ken
author_sort Hirahara, Masanari
collection PubMed
description In the title compound, [Ru(C(10)H(8)N(2))(2)(C(21)H(18)N(4)O(4))](PF(6))(2), the Ru(II) complex cation reveals a slightly distorted octa­hedral coordination. The coordination bonds of the 4,4′-substituted bipyridyl donors [Ru—N = 2.038 (3) and 2.051 (3) Å] are shorter than those of the 2,2′-bipyridyl donors [Ru—N1 = 2.065 (3)–2.077 (3) Å], due to the electron-withdrawing effects of the substituents at the 4,4′-positions. The angles between the pyridyl planes of the three bipyridyl ligands are 1.5 (2), 6.3 (3) and 8.7 (2)°, respectively. The cations are connected by anions via N—H⋯F inter­actions.
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spelling pubmed-29684002010-12-30 Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphen­yl)carbamo­yl]-2,2′-bi­pyridine-4-carboxyl­ate}ruthenium(II) bis­[hexa­fluorido­phosphate(V)] Hirahara, Masanari Masaoka, Shigeyuki Sakai, Ken Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(C(10)H(8)N(2))(2)(C(21)H(18)N(4)O(4))](PF(6))(2), the Ru(II) complex cation reveals a slightly distorted octa­hedral coordination. The coordination bonds of the 4,4′-substituted bipyridyl donors [Ru—N = 2.038 (3) and 2.051 (3) Å] are shorter than those of the 2,2′-bipyridyl donors [Ru—N1 = 2.065 (3)–2.077 (3) Å], due to the electron-withdrawing effects of the substituents at the 4,4′-positions. The angles between the pyridyl planes of the three bipyridyl ligands are 1.5 (2), 6.3 (3) and 8.7 (2)°, respectively. The cations are connected by anions via N—H⋯F inter­actions. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968400/ /pubmed/21581819 http://dx.doi.org/10.1107/S1600536809002360 Text en © Hirahara et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hirahara, Masanari
Masaoka, Shigeyuki
Sakai, Ken
Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphen­yl)carbamo­yl]-2,2′-bi­pyridine-4-carboxyl­ate}ruthenium(II) bis­[hexa­fluorido­phosphate(V)]
title Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphen­yl)carbamo­yl]-2,2′-bi­pyridine-4-carboxyl­ate}ruthenium(II) bis­[hexa­fluorido­phosphate(V)]
title_full Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphen­yl)carbamo­yl]-2,2′-bi­pyridine-4-carboxyl­ate}ruthenium(II) bis­[hexa­fluorido­phosphate(V)]
title_fullStr Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphen­yl)carbamo­yl]-2,2′-bi­pyridine-4-carboxyl­ate}ruthenium(II) bis­[hexa­fluorido­phosphate(V)]
title_full_unstemmed Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphen­yl)carbamo­yl]-2,2′-bi­pyridine-4-carboxyl­ate}ruthenium(II) bis­[hexa­fluorido­phosphate(V)]
title_short Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphen­yl)carbamo­yl]-2,2′-bi­pyridine-4-carboxyl­ate}ruthenium(II) bis­[hexa­fluorido­phosphate(V)]
title_sort bis(2,2′-bipyridine){ethyl 4′-[n-(4-carbamoylphen­yl)carbamo­yl]-2,2′-bi­pyridine-4-carboxyl­ate}ruthenium(ii) bis­[hexa­fluorido­phosphate(v)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968400/
https://www.ncbi.nlm.nih.gov/pubmed/21581819
http://dx.doi.org/10.1107/S1600536809002360
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AT masaokashigeyuki bis22bipyridineethyl4n4carbamoylphenylcarbamoyl22bipyridine4carboxylaterutheniumiibishexafluoridophosphatev
AT sakaiken bis22bipyridineethyl4n4carbamoylphenylcarbamoyl22bipyridine4carboxylaterutheniumiibishexafluoridophosphatev

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