fac-Aqua­dichloridotris(tetra­methyl­ene sulfoxide-κS)ruthenium(II)

The title mol­ecule, [RuCl(2)(C(4)H(8)OS)(3)(H(2)O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetra­methyl­ene sulfoxide ligands facial relative to the Ru(II) center. The Ru—Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru—O distance is 2.1540 (19) Å, and the...

Descripción completa

Detalles Bibliográficos
Autores principales: Srivastava, Radhey S., Gonzales, Carlos F., Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968404/
https://www.ncbi.nlm.nih.gov/pubmed/21581777
http://dx.doi.org/10.1107/S1600536809000439
Descripción
Sumario:The title mol­ecule, [RuCl(2)(C(4)H(8)OS)(3)(H(2)O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetra­methyl­ene sulfoxide ligands facial relative to the Ru(II) center. The Ru—Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru—O distance is 2.1540 (19) Å, and the Ru—S distances are in the range 2.2254 (8)–2.2657 (7) Å, with the shortest being that trans to the aqua ligand. The coordinated water mol­ecule forms inter­molecular hydrogen bonds with Cl and sulfoxide O atoms.

Ejemplares similares