fac-Aqua­dichloridotris(tetra­methyl­ene sulfoxide-κS)ruthenium(II)

The title mol­ecule, [RuCl(2)(C(4)H(8)OS)(3)(H(2)O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetra­methyl­ene sulfoxide ligands facial relative to the Ru(II) center. The Ru—Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru—O distance is 2.1540 (19) Å, and the...

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Detalles Bibliográficos
Autores principales: Srivastava, Radhey S., Gonzales, Carlos F., Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968404/
https://www.ncbi.nlm.nih.gov/pubmed/21581777
http://dx.doi.org/10.1107/S1600536809000439
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author Srivastava, Radhey S.
Gonzales, Carlos F.
Fronczek, Frank R.
author_facet Srivastava, Radhey S.
Gonzales, Carlos F.
Fronczek, Frank R.
author_sort Srivastava, Radhey S.
collection PubMed
description The title mol­ecule, [RuCl(2)(C(4)H(8)OS)(3)(H(2)O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetra­methyl­ene sulfoxide ligands facial relative to the Ru(II) center. The Ru—Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru—O distance is 2.1540 (19) Å, and the Ru—S distances are in the range 2.2254 (8)–2.2657 (7) Å, with the shortest being that trans to the aqua ligand. The coordinated water mol­ecule forms inter­molecular hydrogen bonds with Cl and sulfoxide O atoms.
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spelling pubmed-29684042010-12-30 fac-Aqua­dichloridotris(tetra­methyl­ene sulfoxide-κS)ruthenium(II) Srivastava, Radhey S. Gonzales, Carlos F. Fronczek, Frank R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mol­ecule, [RuCl(2)(C(4)H(8)OS)(3)(H(2)O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetra­methyl­ene sulfoxide ligands facial relative to the Ru(II) center. The Ru—Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru—O distance is 2.1540 (19) Å, and the Ru—S distances are in the range 2.2254 (8)–2.2657 (7) Å, with the shortest being that trans to the aqua ligand. The coordinated water mol­ecule forms inter­molecular hydrogen bonds with Cl and sulfoxide O atoms. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968404/ /pubmed/21581777 http://dx.doi.org/10.1107/S1600536809000439 Text en © Srivastava et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Srivastava, Radhey S.
Gonzales, Carlos F.
Fronczek, Frank R.
fac-Aqua­dichloridotris(tetra­methyl­ene sulfoxide-κS)ruthenium(II)
title fac-Aqua­dichloridotris(tetra­methyl­ene sulfoxide-κS)ruthenium(II)
title_full fac-Aqua­dichloridotris(tetra­methyl­ene sulfoxide-κS)ruthenium(II)
title_fullStr fac-Aqua­dichloridotris(tetra­methyl­ene sulfoxide-κS)ruthenium(II)
title_full_unstemmed fac-Aqua­dichloridotris(tetra­methyl­ene sulfoxide-κS)ruthenium(II)
title_short fac-Aqua­dichloridotris(tetra­methyl­ene sulfoxide-κS)ruthenium(II)
title_sort fac-aqua­dichloridotris(tetra­methyl­ene sulfoxide-κs)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968404/
https://www.ncbi.nlm.nih.gov/pubmed/21581777
http://dx.doi.org/10.1107/S1600536809000439
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AT fronczekfrankr facaquadichloridotristetramethylenesulfoxideksrutheniumii

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