Diaqua­(5-methyl-1H-pyrazole-3-carboxyl­ato)(4-nitro­benzoato)copper(II)

In the title complex, [Cu(C(7)H(4)NO(4))(C(5)H(5)N(2)O(2))(H(2)O)(2)], the Cu(II) ion is coordinated in a slightly distorted square-pyramidal enviroment. The basal plane is formed by an N atom and an O atom from a 5-methyl-1H-pyrazole-3-carboxyl­ate ligand and by two O atoms from two water ligands....

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Detalles Bibliográficos
Autores principales: Hu, Fei-long, Yin, Xian-hong, Feng, Yu, Mi, Yan, Zhang, Shan-shan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968408/
https://www.ncbi.nlm.nih.gov/pubmed/21581806
http://dx.doi.org/10.1107/S160053680900169X
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author Hu, Fei-long
Yin, Xian-hong
Feng, Yu
Mi, Yan
Zhang, Shan-shan
author_facet Hu, Fei-long
Yin, Xian-hong
Feng, Yu
Mi, Yan
Zhang, Shan-shan
author_sort Hu, Fei-long
collection PubMed
description In the title complex, [Cu(C(7)H(4)NO(4))(C(5)H(5)N(2)O(2))(H(2)O)(2)], the Cu(II) ion is coordinated in a slightly distorted square-pyramidal enviroment. The basal plane is formed by an N atom and an O atom from a 5-methyl-1H-pyrazole-3-carboxyl­ate ligand and by two O atoms from two water ligands. The apical position is occupied by a carboxylate O atom from a 4-nitro­benzoate ligand. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link complex moleclues, forming extended chains parallel to the a axis.
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spelling pubmed-29684082010-12-30 Diaqua­(5-methyl-1H-pyrazole-3-carboxyl­ato)(4-nitro­benzoato)copper(II) Hu, Fei-long Yin, Xian-hong Feng, Yu Mi, Yan Zhang, Shan-shan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(7)H(4)NO(4))(C(5)H(5)N(2)O(2))(H(2)O)(2)], the Cu(II) ion is coordinated in a slightly distorted square-pyramidal enviroment. The basal plane is formed by an N atom and an O atom from a 5-methyl-1H-pyrazole-3-carboxyl­ate ligand and by two O atoms from two water ligands. The apical position is occupied by a carboxylate O atom from a 4-nitro­benzoate ligand. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link complex moleclues, forming extended chains parallel to the a axis. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968408/ /pubmed/21581806 http://dx.doi.org/10.1107/S160053680900169X Text en © Hu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Fei-long
Yin, Xian-hong
Feng, Yu
Mi, Yan
Zhang, Shan-shan
Diaqua­(5-methyl-1H-pyrazole-3-carboxyl­ato)(4-nitro­benzoato)copper(II)
title Diaqua­(5-methyl-1H-pyrazole-3-carboxyl­ato)(4-nitro­benzoato)copper(II)
title_full Diaqua­(5-methyl-1H-pyrazole-3-carboxyl­ato)(4-nitro­benzoato)copper(II)
title_fullStr Diaqua­(5-methyl-1H-pyrazole-3-carboxyl­ato)(4-nitro­benzoato)copper(II)
title_full_unstemmed Diaqua­(5-methyl-1H-pyrazole-3-carboxyl­ato)(4-nitro­benzoato)copper(II)
title_short Diaqua­(5-methyl-1H-pyrazole-3-carboxyl­ato)(4-nitro­benzoato)copper(II)
title_sort diaqua­(5-methyl-1h-pyrazole-3-carboxyl­ato)(4-nitro­benzoato)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968408/
https://www.ncbi.nlm.nih.gov/pubmed/21581806
http://dx.doi.org/10.1107/S160053680900169X
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