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Bis{2-formyl-4-methyl-6-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II)
The title compound, [Ni(C(25)H(19)N(4)O(2))(2)], which was obtained by the reaction of nickel(II) perchlorate with 2,6-diformyl-4-methylphenol and (tri-2-pyridylmethyl)amine in methanol solution, is a discrete monometallic complex. The Ni(II) atom is six-coordinated by the phenolate O, imine N and...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968412/ https://www.ncbi.nlm.nih.gov/pubmed/21581821 http://dx.doi.org/10.1107/S160053680900244X |
| _version_ | 1782189868070207488 |
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| author | Dang, Yan-Qiu Yang, Hong-Jun Tian, Lai-Jin |
| author_facet | Dang, Yan-Qiu Yang, Hong-Jun Tian, Lai-Jin |
| author_sort | Dang, Yan-Qiu |
| collection | PubMed |
| description | The title compound, [Ni(C(25)H(19)N(4)O(2))(2)], which was obtained by the reaction of nickel(II) perchlorate with 2,6-diformyl-4-methylphenol and (tri-2-pyridylmethyl)amine in methanol solution, is a discrete monometallic complex. The Ni(II) atom is six-coordinated by the phenolate O, imine N and pyridine N atoms from two tridentate Schiff base ligands in a distorted NiN(4)O(2) octahedral geometry. The dihedral angles between the noncoordinated pyridyl rings of each ligand are 72.95 (8) and 69.59 (7)°. |
| format | Text |
| id | pubmed-2968412 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29684122010-12-30 Bis{2-formyl-4-methyl-6-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II) Dang, Yan-Qiu Yang, Hong-Jun Tian, Lai-Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(25)H(19)N(4)O(2))(2)], which was obtained by the reaction of nickel(II) perchlorate with 2,6-diformyl-4-methylphenol and (tri-2-pyridylmethyl)amine in methanol solution, is a discrete monometallic complex. The Ni(II) atom is six-coordinated by the phenolate O, imine N and pyridine N atoms from two tridentate Schiff base ligands in a distorted NiN(4)O(2) octahedral geometry. The dihedral angles between the noncoordinated pyridyl rings of each ligand are 72.95 (8) and 69.59 (7)°. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968412/ /pubmed/21581821 http://dx.doi.org/10.1107/S160053680900244X Text en © Dang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Dang, Yan-Qiu Yang, Hong-Jun Tian, Lai-Jin Bis{2-formyl-4-methyl-6-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II) |
| title | Bis{2-formyl-4-methyl-6-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II) |
| title_full | Bis{2-formyl-4-methyl-6-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II) |
| title_fullStr | Bis{2-formyl-4-methyl-6-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II) |
| title_full_unstemmed | Bis{2-formyl-4-methyl-6-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II) |
| title_short | Bis{2-formyl-4-methyl-6-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II) |
| title_sort | bis{2-formyl-4-methyl-6-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968412/ https://www.ncbi.nlm.nih.gov/pubmed/21581821 http://dx.doi.org/10.1107/S160053680900244X |
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