Chloridobis[diphenyl­glyoximato(1–)-κ(2) N,N′](1H-imidazole-κN (3))cobalt(III) hemihydrate

The Co centre in the title compound, [Co(C(14)H(11)N(2)O(2))(2)Cl(C(3)H(4)N(2))]·0.5H(2)O, shows a slightly distorted octa­hedral coordination geometry. The glyoximate units of the mol­ecule are linked by O—H⋯O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal packi...

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Detalles Bibliográficos
Autores principales: Meera, P., Revathi, C., Dayalan, A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968413/
https://www.ncbi.nlm.nih.gov/pubmed/21581756
http://dx.doi.org/10.1107/S160053680804347X
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author Meera, P.
Revathi, C.
Dayalan, A.
author_facet Meera, P.
Revathi, C.
Dayalan, A.
author_sort Meera, P.
collection PubMed
description The Co centre in the title compound, [Co(C(14)H(11)N(2)O(2))(2)Cl(C(3)H(4)N(2))]·0.5H(2)O, shows a slightly distorted octa­hedral coordination geometry. The glyoximate units of the mol­ecule are linked by O—H⋯O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal packing is stabilized through inter­molecular N—H⋯O, N—H⋯N and O—H⋯Cl hydrogen bonds. The uncoordinated water mol­ecule shows half-occupation.
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spelling pubmed-29684132010-12-30 Chloridobis[diphenyl­glyoximato(1–)-κ(2) N,N′](1H-imidazole-κN (3))cobalt(III) hemihydrate Meera, P. Revathi, C. Dayalan, A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co centre in the title compound, [Co(C(14)H(11)N(2)O(2))(2)Cl(C(3)H(4)N(2))]·0.5H(2)O, shows a slightly distorted octa­hedral coordination geometry. The glyoximate units of the mol­ecule are linked by O—H⋯O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal packing is stabilized through inter­molecular N—H⋯O, N—H⋯N and O—H⋯Cl hydrogen bonds. The uncoordinated water mol­ecule shows half-occupation. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968413/ /pubmed/21581756 http://dx.doi.org/10.1107/S160053680804347X Text en © Meera et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meera, P.
Revathi, C.
Dayalan, A.
Chloridobis[diphenyl­glyoximato(1–)-κ(2) N,N′](1H-imidazole-κN (3))cobalt(III) hemihydrate
title Chloridobis[diphenyl­glyoximato(1–)-κ(2) N,N′](1H-imidazole-κN (3))cobalt(III) hemihydrate
title_full Chloridobis[diphenyl­glyoximato(1–)-κ(2) N,N′](1H-imidazole-κN (3))cobalt(III) hemihydrate
title_fullStr Chloridobis[diphenyl­glyoximato(1–)-κ(2) N,N′](1H-imidazole-κN (3))cobalt(III) hemihydrate
title_full_unstemmed Chloridobis[diphenyl­glyoximato(1–)-κ(2) N,N′](1H-imidazole-κN (3))cobalt(III) hemihydrate
title_short Chloridobis[diphenyl­glyoximato(1–)-κ(2) N,N′](1H-imidazole-κN (3))cobalt(III) hemihydrate
title_sort chloridobis[diphenyl­glyoximato(1–)-κ(2) n,n′](1h-imidazole-κn (3))cobalt(iii) hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968413/
https://www.ncbi.nlm.nih.gov/pubmed/21581756
http://dx.doi.org/10.1107/S160053680804347X
work_keys_str_mv AT meerap chloridobisdiphenylglyoximato1k2nn1himidazolekn3cobaltiiihemihydrate
AT revathic chloridobisdiphenylglyoximato1k2nn1himidazolekn3cobaltiiihemihydrate
AT dayalana chloridobisdiphenylglyoximato1k2nn1himidazolekn3cobaltiiihemihydrate

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