(2,2-Dichloro­vinyl)ferrocene

The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of π-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting materia...

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Detalles Bibliográficos
Autores principales: Clément, Sébastien, Guyard, Laurent, Knorr, Michael, Gessner, Viktoria H., Strohmann, Carsten
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968422/
https://www.ncbi.nlm.nih.gov/pubmed/21582103
http://dx.doi.org/10.1107/S1600536809006102
Descripción
Sumario:The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of π-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclo­penta­dienide ring are almost parallel, with an angle between the best planes of only 10.6 (4)°.

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