(2,2-Dichloro­vinyl)ferrocene

The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of π-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting materia...

Descripción completa

Detalles Bibliográficos
Autores principales: Clément, Sébastien, Guyard, Laurent, Knorr, Michael, Gessner, Viktoria H., Strohmann, Carsten
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968422/
https://www.ncbi.nlm.nih.gov/pubmed/21582103
http://dx.doi.org/10.1107/S1600536809006102
_version_ 1782189871620685824
author Clément, Sébastien
Guyard, Laurent
Knorr, Michael
Gessner, Viktoria H.
Strohmann, Carsten
author_facet Clément, Sébastien
Guyard, Laurent
Knorr, Michael
Gessner, Viktoria H.
Strohmann, Carsten
author_sort Clément, Sébastien
collection PubMed
description The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of π-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclo­penta­dienide ring are almost parallel, with an angle between the best planes of only 10.6 (4)°.
format Text
id pubmed-2968422
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29684222010-12-30 (2,2-Dichloro­vinyl)ferrocene Clément, Sébastien Guyard, Laurent Knorr, Michael Gessner, Viktoria H. Strohmann, Carsten Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of π-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclo­penta­dienide ring are almost parallel, with an angle between the best planes of only 10.6 (4)°. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968422/ /pubmed/21582103 http://dx.doi.org/10.1107/S1600536809006102 Text en © Clément et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Clément, Sébastien
Guyard, Laurent
Knorr, Michael
Gessner, Viktoria H.
Strohmann, Carsten
(2,2-Dichloro­vinyl)ferrocene
title (2,2-Dichloro­vinyl)ferrocene
title_full (2,2-Dichloro­vinyl)ferrocene
title_fullStr (2,2-Dichloro­vinyl)ferrocene
title_full_unstemmed (2,2-Dichloro­vinyl)ferrocene
title_short (2,2-Dichloro­vinyl)ferrocene
title_sort (2,2-dichloro­vinyl)ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968422/
https://www.ncbi.nlm.nih.gov/pubmed/21582103
http://dx.doi.org/10.1107/S1600536809006102
work_keys_str_mv AT clementsebastien 22dichlorovinylferrocene
AT guyardlaurent 22dichlorovinylferrocene
AT knorrmichael 22dichlorovinylferrocene
AT gessnerviktoriah 22dichlorovinylferrocene
AT strohmanncarsten 22dichlorovinylferrocene

Ejemplares similares