Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate

The title compound, [PtCl(2)(C(13)H(11)O(2)P)(2)]·CHCl(3), has a rare PtCl(2) bridging of two dibenzooxaphospho­rine ligands through the metal atom. The Pt(II) ion is in a slightly distorted square-planar environment. The trichloro­methane solvent mol­ecule shows rotational disorder (major occupancy...

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Detalles Bibliográficos
Autores principales: Holczbauer, Tamás, Keglevich, György, Kerényi, Andrea, Czugler, Mátyás
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968428/
https://www.ncbi.nlm.nih.gov/pubmed/21582112
http://dx.doi.org/10.1107/S1600536809006643
Descripción
Sumario:The title compound, [PtCl(2)(C(13)H(11)O(2)P)(2)]·CHCl(3), has a rare PtCl(2) bridging of two dibenzooxaphospho­rine ligands through the metal atom. The Pt(II) ion is in a slightly distorted square-planar environment. The trichloro­methane solvent mol­ecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent mol­ecule is linked to the complex mol­ecule via inter­molecular bifurcated C—H⋯Cl and C—H⋯O hydrogen bonds. The crystal structure is further stabilized by π–π inter­actions involving the benzene rings, with a centroid–centroid distance of 3.658 (8) Å.

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