Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate

The title compound, [PtCl(2)(C(13)H(11)O(2)P)(2)]·CHCl(3), has a rare PtCl(2) bridging of two dibenzooxaphospho­rine ligands through the metal atom. The Pt(II) ion is in a slightly distorted square-planar environment. The trichloro­methane solvent mol­ecule shows rotational disorder (major occupancy...

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Autores principales: Holczbauer, Tamás, Keglevich, György, Kerényi, Andrea, Czugler, Mátyás
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968428/
https://www.ncbi.nlm.nih.gov/pubmed/21582112
http://dx.doi.org/10.1107/S1600536809006643
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author Holczbauer, Tamás
Keglevich, György
Kerényi, Andrea
Czugler, Mátyás
author_facet Holczbauer, Tamás
Keglevich, György
Kerényi, Andrea
Czugler, Mátyás
author_sort Holczbauer, Tamás
collection PubMed
description The title compound, [PtCl(2)(C(13)H(11)O(2)P)(2)]·CHCl(3), has a rare PtCl(2) bridging of two dibenzooxaphospho­rine ligands through the metal atom. The Pt(II) ion is in a slightly distorted square-planar environment. The trichloro­methane solvent mol­ecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent mol­ecule is linked to the complex mol­ecule via inter­molecular bifurcated C—H⋯Cl and C—H⋯O hydrogen bonds. The crystal structure is further stabilized by π–π inter­actions involving the benzene rings, with a centroid–centroid distance of 3.658 (8) Å.
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spelling pubmed-29684282010-12-30 Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate Holczbauer, Tamás Keglevich, György Kerényi, Andrea Czugler, Mátyás Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PtCl(2)(C(13)H(11)O(2)P)(2)]·CHCl(3), has a rare PtCl(2) bridging of two dibenzooxaphospho­rine ligands through the metal atom. The Pt(II) ion is in a slightly distorted square-planar environment. The trichloro­methane solvent mol­ecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent mol­ecule is linked to the complex mol­ecule via inter­molecular bifurcated C—H⋯Cl and C—H⋯O hydrogen bonds. The crystal structure is further stabilized by π–π inter­actions involving the benzene rings, with a centroid–centroid distance of 3.658 (8) Å. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968428/ /pubmed/21582112 http://dx.doi.org/10.1107/S1600536809006643 Text en © Holczbauer et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Holczbauer, Tamás
Keglevich, György
Kerényi, Andrea
Czugler, Mátyás
Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate
title Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate
title_full Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate
title_fullStr Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate
title_full_unstemmed Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate
title_short Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate
title_sort dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κp)platinum(ii) trichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968428/
https://www.ncbi.nlm.nih.gov/pubmed/21582112
http://dx.doi.org/10.1107/S1600536809006643
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