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Diaqua­bis[5-(2-pyrid­yl)-1H-tetra­zolato-κ(2) N (1),N (5)]cobalt(II)

In the title compound, [Co(C(6)H(4)N(5))(2)(H(2)O)(2)], the Co atom is bonded to two water mol­ecules and two bidentate 5-(2-pyrid­yl)tetra­zolate ligands resulting in a slightly distorted octa­hedral CoN(4)O(2) coordination geometry. The Co(II) cation is situated on a crystallographic center of inv...

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Detalles Bibliográficos
Autores principales: Sun, Zhen-Hai, Meng, Ling-Bo, Lin, Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968432/
https://www.ncbi.nlm.nih.gov/pubmed/21582066
http://dx.doi.org/10.1107/S160053680900470X
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author Sun, Zhen-Hai
Meng, Ling-Bo
Lin, Hua
author_facet Sun, Zhen-Hai
Meng, Ling-Bo
Lin, Hua
author_sort Sun, Zhen-Hai
collection PubMed
description In the title compound, [Co(C(6)H(4)N(5))(2)(H(2)O)(2)], the Co atom is bonded to two water mol­ecules and two bidentate 5-(2-pyrid­yl)tetra­zolate ligands resulting in a slightly distorted octa­hedral CoN(4)O(2) coordination geometry. The Co(II) cation is situated on a crystallographic center of inversion. The asymmetric unit therefore comprises one-half of the mol­ecule. The four N atoms belonging to two bidentate 5-(2-pyrid­yl)tetra­zolate ligands lie in the equatorial plane and the two associated water mol­ecules are observed in the axial coordination sites. The crystal structure exhibits a three-dimensional supra­molecular network assembled by inter­molecular O—H⋯N hydrogen bonds.
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spelling pubmed-29684322010-12-30 Diaqua­bis[5-(2-pyrid­yl)-1H-tetra­zolato-κ(2) N (1),N (5)]cobalt(II) Sun, Zhen-Hai Meng, Ling-Bo Lin, Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(6)H(4)N(5))(2)(H(2)O)(2)], the Co atom is bonded to two water mol­ecules and two bidentate 5-(2-pyrid­yl)tetra­zolate ligands resulting in a slightly distorted octa­hedral CoN(4)O(2) coordination geometry. The Co(II) cation is situated on a crystallographic center of inversion. The asymmetric unit therefore comprises one-half of the mol­ecule. The four N atoms belonging to two bidentate 5-(2-pyrid­yl)tetra­zolate ligands lie in the equatorial plane and the two associated water mol­ecules are observed in the axial coordination sites. The crystal structure exhibits a three-dimensional supra­molecular network assembled by inter­molecular O—H⋯N hydrogen bonds. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968432/ /pubmed/21582066 http://dx.doi.org/10.1107/S160053680900470X Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Zhen-Hai
Meng, Ling-Bo
Lin, Hua
Diaqua­bis[5-(2-pyrid­yl)-1H-tetra­zolato-κ(2) N (1),N (5)]cobalt(II)
title Diaqua­bis[5-(2-pyrid­yl)-1H-tetra­zolato-κ(2) N (1),N (5)]cobalt(II)
title_full Diaqua­bis[5-(2-pyrid­yl)-1H-tetra­zolato-κ(2) N (1),N (5)]cobalt(II)
title_fullStr Diaqua­bis[5-(2-pyrid­yl)-1H-tetra­zolato-κ(2) N (1),N (5)]cobalt(II)
title_full_unstemmed Diaqua­bis[5-(2-pyrid­yl)-1H-tetra­zolato-κ(2) N (1),N (5)]cobalt(II)
title_short Diaqua­bis[5-(2-pyrid­yl)-1H-tetra­zolato-κ(2) N (1),N (5)]cobalt(II)
title_sort diaqua­bis[5-(2-pyrid­yl)-1h-tetra­zolato-κ(2) n (1),n (5)]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968432/
https://www.ncbi.nlm.nih.gov/pubmed/21582066
http://dx.doi.org/10.1107/S160053680900470X
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