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Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ(2) N (1),N (5)]cobalt(II)
In the title compound, [Co(C(6)H(4)N(5))(2)(H(2)O)(2)], the Co atom is bonded to two water molecules and two bidentate 5-(2-pyridyl)tetrazolate ligands resulting in a slightly distorted octahedral CoN(4)O(2) coordination geometry. The Co(II) cation is situated on a crystallographic center of inv...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968432/ https://www.ncbi.nlm.nih.gov/pubmed/21582066 http://dx.doi.org/10.1107/S160053680900470X |
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author | Sun, Zhen-Hai Meng, Ling-Bo Lin, Hua |
author_facet | Sun, Zhen-Hai Meng, Ling-Bo Lin, Hua |
author_sort | Sun, Zhen-Hai |
collection | PubMed |
description | In the title compound, [Co(C(6)H(4)N(5))(2)(H(2)O)(2)], the Co atom is bonded to two water molecules and two bidentate 5-(2-pyridyl)tetrazolate ligands resulting in a slightly distorted octahedral CoN(4)O(2) coordination geometry. The Co(II) cation is situated on a crystallographic center of inversion. The asymmetric unit therefore comprises one-half of the molecule. The four N atoms belonging to two bidentate 5-(2-pyridyl)tetrazolate ligands lie in the equatorial plane and the two associated water molecules are observed in the axial coordination sites. The crystal structure exhibits a three-dimensional supramolecular network assembled by intermolecular O—H⋯N hydrogen bonds. |
format | Text |
id | pubmed-2968432 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29684322010-12-30 Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ(2) N (1),N (5)]cobalt(II) Sun, Zhen-Hai Meng, Ling-Bo Lin, Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(6)H(4)N(5))(2)(H(2)O)(2)], the Co atom is bonded to two water molecules and two bidentate 5-(2-pyridyl)tetrazolate ligands resulting in a slightly distorted octahedral CoN(4)O(2) coordination geometry. The Co(II) cation is situated on a crystallographic center of inversion. The asymmetric unit therefore comprises one-half of the molecule. The four N atoms belonging to two bidentate 5-(2-pyridyl)tetrazolate ligands lie in the equatorial plane and the two associated water molecules are observed in the axial coordination sites. The crystal structure exhibits a three-dimensional supramolecular network assembled by intermolecular O—H⋯N hydrogen bonds. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968432/ /pubmed/21582066 http://dx.doi.org/10.1107/S160053680900470X Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sun, Zhen-Hai Meng, Ling-Bo Lin, Hua Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ(2) N (1),N (5)]cobalt(II) |
title | Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ(2)
N
(1),N
(5)]cobalt(II) |
title_full | Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ(2)
N
(1),N
(5)]cobalt(II) |
title_fullStr | Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ(2)
N
(1),N
(5)]cobalt(II) |
title_full_unstemmed | Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ(2)
N
(1),N
(5)]cobalt(II) |
title_short | Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ(2)
N
(1),N
(5)]cobalt(II) |
title_sort | diaquabis[5-(2-pyridyl)-1h-tetrazolato-κ(2)
n
(1),n
(5)]cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968432/ https://www.ncbi.nlm.nih.gov/pubmed/21582066 http://dx.doi.org/10.1107/S160053680900470X |
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