Li(3)Al(MoO(2))(2)O(2)(AsO(4))(2)

Single crystals of trilithium(I) aluminium(III) bis­[dioxidomolybdenum(VI)] dioxide bis­[arsenate(V)], Li(3)AlMo(2)As(2)O(14), have been prepared by solid-state reaction at 788 K. The structure consists of AsO(4) tetra­hedra, AlO(6) octa­hedra and Mo(2)O(10) groups sharing corners to form a three-di...

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Detalles Bibliográficos
Autores principales: Hajji, Mounir, Zid, Mohamed Faouzi, Driss, Ahmed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968439/
https://www.ncbi.nlm.nih.gov/pubmed/21582037
http://dx.doi.org/10.1107/S160053680900631X
Descripción
Sumario:Single crystals of trilithium(I) aluminium(III) bis­[dioxidomolybdenum(VI)] dioxide bis­[arsenate(V)], Li(3)AlMo(2)As(2)O(14), have been prepared by solid-state reaction at 788 K. The structure consists of AsO(4) tetra­hedra, AlO(6) octa­hedra and Mo(2)O(10) groups sharing corners to form a three-dimensional framework containing channels running respectively along the [100] and [010] directions, where the Li(+) ions are located. This structure is compared with compounds having (MX (2)O(12))(n) chains (M = Mo, Al and X = P, As) and others containing M (2)O(10) (M = Mo, Fe) dimers.

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