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Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))manganese(II)

The title compound, [Mn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one Mn(II) atom lying on an inversion centre, two 4-formyl­benzoate and two diethyl­nicotinamide ligands and two coordinated water mol­ecules. All ligands are monodentate. The four O atoms around the Mn atom form a sli...

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Autores principales: Sertçelik, Mustafa, Tercan, Barış, Şahin, Ertan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968440/
https://www.ncbi.nlm.nih.gov/pubmed/21582097
http://dx.doi.org/10.1107/S1600536809006047
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author Sertçelik, Mustafa
Tercan, Barış
Şahin, Ertan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Sertçelik, Mustafa
Tercan, Barış
Şahin, Ertan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Sertçelik, Mustafa
collection PubMed
description The title compound, [Mn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one Mn(II) atom lying on an inversion centre, two 4-formyl­benzoate and two diethyl­nicotinamide ligands and two coordinated water mol­ecules. All ligands are monodentate. The four O atoms around the Mn atom form a slightly distorted equatorial plane, while the distorted octa­hedral coordination is completed by the two N atoms in the axial positions. An intra­molecular O—H⋯O hydrogen bond occurs in the complex. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules through an R (2) (2)(16) ring motif, forming a one-dimensional chain along the a axis. The π–π contact between the pyridyl rings [centroid–centroid distance = 3.629 (2) Å] may further stabilize the structure.
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spelling pubmed-29684402010-12-30 Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))manganese(II) Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one Mn(II) atom lying on an inversion centre, two 4-formyl­benzoate and two diethyl­nicotinamide ligands and two coordinated water mol­ecules. All ligands are monodentate. The four O atoms around the Mn atom form a slightly distorted equatorial plane, while the distorted octa­hedral coordination is completed by the two N atoms in the axial positions. An intra­molecular O—H⋯O hydrogen bond occurs in the complex. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules through an R (2) (2)(16) ring motif, forming a one-dimensional chain along the a axis. The π–π contact between the pyridyl rings [centroid–centroid distance = 3.629 (2) Å] may further stabilize the structure. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968440/ /pubmed/21582097 http://dx.doi.org/10.1107/S1600536809006047 Text en © Sertçelik et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sertçelik, Mustafa
Tercan, Barış
Şahin, Ertan
Necefoğlu, Hacali
Hökelek, Tuncer
Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))manganese(II)
title Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))manganese(II)
title_full Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))manganese(II)
title_fullStr Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))manganese(II)
title_full_unstemmed Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))manganese(II)
title_short Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))manganese(II)
title_sort diaqua­bis(n,n-diethyl­nicotinamide-κn (1))bis­(4-formyl­benzoato-κo (1))manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968440/
https://www.ncbi.nlm.nih.gov/pubmed/21582097
http://dx.doi.org/10.1107/S1600536809006047
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