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Diaquabis(N,N-diethylnicotinamide-κN (1))bis(4-formylbenzoato-κO (1))manganese(II)
The title compound, [Mn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one Mn(II) atom lying on an inversion centre, two 4-formylbenzoate and two diethylnicotinamide ligands and two coordinated water molecules. All ligands are monodentate. The four O atoms around the Mn atom form a sli...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968440/ https://www.ncbi.nlm.nih.gov/pubmed/21582097 http://dx.doi.org/10.1107/S1600536809006047 |
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author | Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Sertçelik, Mustafa |
collection | PubMed |
description | The title compound, [Mn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one Mn(II) atom lying on an inversion centre, two 4-formylbenzoate and two diethylnicotinamide ligands and two coordinated water molecules. All ligands are monodentate. The four O atoms around the Mn atom form a slightly distorted equatorial plane, while the distorted octahedral coordination is completed by the two N atoms in the axial positions. An intramolecular O—H⋯O hydrogen bond occurs in the complex. In the crystal structure, O—H⋯O hydrogen bonds link the molecules through an R (2) (2)(16) ring motif, forming a one-dimensional chain along the a axis. The π–π contact between the pyridyl rings [centroid–centroid distance = 3.629 (2) Å] may further stabilize the structure. |
format | Text |
id | pubmed-2968440 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29684402010-12-30 Diaquabis(N,N-diethylnicotinamide-κN (1))bis(4-formylbenzoato-κO (1))manganese(II) Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one Mn(II) atom lying on an inversion centre, two 4-formylbenzoate and two diethylnicotinamide ligands and two coordinated water molecules. All ligands are monodentate. The four O atoms around the Mn atom form a slightly distorted equatorial plane, while the distorted octahedral coordination is completed by the two N atoms in the axial positions. An intramolecular O—H⋯O hydrogen bond occurs in the complex. In the crystal structure, O—H⋯O hydrogen bonds link the molecules through an R (2) (2)(16) ring motif, forming a one-dimensional chain along the a axis. The π–π contact between the pyridyl rings [centroid–centroid distance = 3.629 (2) Å] may further stabilize the structure. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968440/ /pubmed/21582097 http://dx.doi.org/10.1107/S1600536809006047 Text en © Sertçelik et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer Diaquabis(N,N-diethylnicotinamide-κN (1))bis(4-formylbenzoato-κO (1))manganese(II) |
title | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO
(1))manganese(II) |
title_full | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO
(1))manganese(II) |
title_fullStr | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO
(1))manganese(II) |
title_full_unstemmed | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO
(1))manganese(II) |
title_short | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO
(1))manganese(II) |
title_sort | diaquabis(n,n-diethylnicotinamide-κn
(1))bis(4-formylbenzoato-κo
(1))manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968440/ https://www.ncbi.nlm.nih.gov/pubmed/21582097 http://dx.doi.org/10.1107/S1600536809006047 |
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