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3,4,5-Trimethyl-2,4,6-triphenyl-4H-thiopyran
The six-membered thiopyran ring in the title compound, C(26)H(24)S, adopts a boat conformation, with the S atom displaced by 0.478 (2) Å and the 3-methylene C atom by 0.644 (2) Å from the plane of the other four sp (2)-hydridized C atoms. The methyl group on the methylene carbon lies in a pseudo-...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968441/ https://www.ncbi.nlm.nih.gov/pubmed/21582258 http://dx.doi.org/10.1107/S1600536809005923 |
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author | Rahmani, Hossein Pirelahi, Hooshang Ng, Seik Weng |
author_facet | Rahmani, Hossein Pirelahi, Hooshang Ng, Seik Weng |
author_sort | Rahmani, Hossein |
collection | PubMed |
description | The six-membered thiopyran ring in the title compound, C(26)H(24)S, adopts a boat conformation, with the S atom displaced by 0.478 (2) Å and the 3-methylene C atom by 0.644 (2) Å from the plane of the other four sp (2)-hydridized C atoms. The methyl group on the methylene carbon lies in a pseudo-equatorial position and the phenyl ring in a pseudo-axial position. |
format | Text |
id | pubmed-2968441 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29684412010-12-30 3,4,5-Trimethyl-2,4,6-triphenyl-4H-thiopyran Rahmani, Hossein Pirelahi, Hooshang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The six-membered thiopyran ring in the title compound, C(26)H(24)S, adopts a boat conformation, with the S atom displaced by 0.478 (2) Å and the 3-methylene C atom by 0.644 (2) Å from the plane of the other four sp (2)-hydridized C atoms. The methyl group on the methylene carbon lies in a pseudo-equatorial position and the phenyl ring in a pseudo-axial position. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968441/ /pubmed/21582258 http://dx.doi.org/10.1107/S1600536809005923 Text en © Rahmani et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rahmani, Hossein Pirelahi, Hooshang Ng, Seik Weng 3,4,5-Trimethyl-2,4,6-triphenyl-4H-thiopyran |
title | 3,4,5-Trimethyl-2,4,6-triphenyl-4H-thiopyran |
title_full | 3,4,5-Trimethyl-2,4,6-triphenyl-4H-thiopyran |
title_fullStr | 3,4,5-Trimethyl-2,4,6-triphenyl-4H-thiopyran |
title_full_unstemmed | 3,4,5-Trimethyl-2,4,6-triphenyl-4H-thiopyran |
title_short | 3,4,5-Trimethyl-2,4,6-triphenyl-4H-thiopyran |
title_sort | 3,4,5-trimethyl-2,4,6-triphenyl-4h-thiopyran |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968441/ https://www.ncbi.nlm.nih.gov/pubmed/21582258 http://dx.doi.org/10.1107/S1600536809005923 |
work_keys_str_mv | AT rahmanihossein 345trimethyl246triphenyl4hthiopyran AT pirelahihooshang 345trimethyl246triphenyl4hthiopyran AT ngseikweng 345trimethyl246triphenyl4hthiopyran |