Bis(5-chloro­quinolin-8-olato-κ(2) N,O)bis­(propan-2-olato-κO)titanium(IV)

The Ti(IV) atom in the title compound, [Ti(C(9)H(5)ClNO)(2)(C(3)H(7)O)(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa­hedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups...

Descripción completa

Detalles Bibliográficos
Autores principales: Fazaeli, Yousef, Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968443/
https://www.ncbi.nlm.nih.gov/pubmed/21582059
http://dx.doi.org/10.1107/S1600536809004383
_version_ 1782189877488517120
author Fazaeli, Yousef
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Fazaeli, Yousef
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Fazaeli, Yousef
collection PubMed
description The Ti(IV) atom in the title compound, [Ti(C(9)H(5)ClNO)(2)(C(3)H(7)O)(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa­hedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733 (8):0.267 (8).
format Text
id pubmed-2968443
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29684432010-12-30 Bis(5-chloro­quinolin-8-olato-κ(2) N,O)bis­(propan-2-olato-κO)titanium(IV) Fazaeli, Yousef Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ti(IV) atom in the title compound, [Ti(C(9)H(5)ClNO)(2)(C(3)H(7)O)(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa­hedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733 (8):0.267 (8). International Union of Crystallography 2009-02-13 /pmc/articles/PMC2968443/ /pubmed/21582059 http://dx.doi.org/10.1107/S1600536809004383 Text en © Fazaeli et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fazaeli, Yousef
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
Bis(5-chloro­quinolin-8-olato-κ(2) N,O)bis­(propan-2-olato-κO)titanium(IV)
title Bis(5-chloro­quinolin-8-olato-κ(2) N,O)bis­(propan-2-olato-κO)titanium(IV)
title_full Bis(5-chloro­quinolin-8-olato-κ(2) N,O)bis­(propan-2-olato-κO)titanium(IV)
title_fullStr Bis(5-chloro­quinolin-8-olato-κ(2) N,O)bis­(propan-2-olato-κO)titanium(IV)
title_full_unstemmed Bis(5-chloro­quinolin-8-olato-κ(2) N,O)bis­(propan-2-olato-κO)titanium(IV)
title_short Bis(5-chloro­quinolin-8-olato-κ(2) N,O)bis­(propan-2-olato-κO)titanium(IV)
title_sort bis(5-chloro­quinolin-8-olato-κ(2) n,o)bis­(propan-2-olato-κo)titanium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968443/
https://www.ncbi.nlm.nih.gov/pubmed/21582059
http://dx.doi.org/10.1107/S1600536809004383
work_keys_str_mv AT fazaeliyousef bis5chloroquinolin8olatok2nobispropan2olatokotitaniumiv
AT najafiezzatollah bis5chloroquinolin8olatok2nobispropan2olatokotitaniumiv
AT aminimostafam bis5chloroquinolin8olatok2nobispropan2olatokotitaniumiv
AT ngseikweng bis5chloroquinolin8olatok2nobispropan2olatokotitaniumiv

Ejemplares similares