[N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)

The title compound, [NiBr(2)(C(27)H(27)NP(2))], was synthesized by the reaction of NiBr(2)(dme) (dme is 1,2-dimethoxy­ethane) with N,N-bis­(diphenyl­phosphino)isopropyl­amine in methanol/tetra­hydro­furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, Ph(2)PN(iPr)P...

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Detalles Bibliográficos
Autores principales: Hapke, Marko, Wöhl, Anina, Peitz, Stephan, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968448/
https://www.ncbi.nlm.nih.gov/pubmed/21582045
http://dx.doi.org/10.1107/S1600536809003936
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author Hapke, Marko
Wöhl, Anina
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_facet Hapke, Marko
Wöhl, Anina
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_sort Hapke, Marko
collection PubMed
description The title compound, [NiBr(2)(C(27)H(27)NP(2))], was synthesized by the reaction of NiBr(2)(dme) (dme is 1,2-dimethoxy­ethane) with N,N-bis­(diphenyl­phosphino)isopropyl­amine in methanol/tetra­hydro­furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, Ph(2)PN(iPr)PPh(2), and two bromide ions in a distorted square-planar geometry.
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spelling pubmed-29684482010-12-30 [N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II) Hapke, Marko Wöhl, Anina Peitz, Stephan Müller, Bernd H. Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [NiBr(2)(C(27)H(27)NP(2))], was synthesized by the reaction of NiBr(2)(dme) (dme is 1,2-dimethoxy­ethane) with N,N-bis­(diphenyl­phosphino)isopropyl­amine in methanol/tetra­hydro­furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, Ph(2)PN(iPr)PPh(2), and two bromide ions in a distorted square-planar geometry. International Union of Crystallography 2009-02-06 /pmc/articles/PMC2968448/ /pubmed/21582045 http://dx.doi.org/10.1107/S1600536809003936 Text en © Hapke et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hapke, Marko
Wöhl, Anina
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
[N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)
title [N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)
title_full [N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)
title_fullStr [N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)
title_full_unstemmed [N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)
title_short [N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)
title_sort [n,n-bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968448/
https://www.ncbi.nlm.nih.gov/pubmed/21582045
http://dx.doi.org/10.1107/S1600536809003936
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