Glycinium hydrogen fumarate glycine solvate monohydrate

In the title compound, C(2)H(6)NO(2) (+)·C(4)H(3)O(4) (−)·C(2)H(5)NO(2)·H(2)O, the asymmetric unit contains two glycine residues, one protonated and one in the zwitterionic form, a hydrogen fumarate anion and a water mol­ecule. Through N—H⋯O and O—H⋯O hydrogen bonds, mol­ecules assemble in layers pa...

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Autores principales: Natarajan, S., Kalyanasundar, A., Suresh, J., Dhas, S. A. Martin Britto, Lakshman, P. L. Nilantha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968449/
https://www.ncbi.nlm.nih.gov/pubmed/21582134
http://dx.doi.org/10.1107/S1600536809001974
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author Natarajan, S.
Kalyanasundar, A.
Suresh, J.
Dhas, S. A. Martin Britto
Lakshman, P. L. Nilantha
author_facet Natarajan, S.
Kalyanasundar, A.
Suresh, J.
Dhas, S. A. Martin Britto
Lakshman, P. L. Nilantha
author_sort Natarajan, S.
collection PubMed
description In the title compound, C(2)H(6)NO(2) (+)·C(4)H(3)O(4) (−)·C(2)H(5)NO(2)·H(2)O, the asymmetric unit contains two glycine residues, one protonated and one in the zwitterionic form, a hydrogen fumarate anion and a water mol­ecule. Through N—H⋯O and O—H⋯O hydrogen bonds, mol­ecules assemble in layers parallel to the (10[Image: see text]) plane, one layer of hydrogen fumarate anions alternating with two layers of glycine mol­ecules. In each glycine layer, hydrogen bonds generate an R (4) (4)(19) graph-set motif. Further hydrogen bonds involving the water mol­ecule and the hydrogen fumarate anions result in the formation of a three-dimensional network.
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spelling pubmed-29684492010-12-30 Glycinium hydrogen fumarate glycine solvate monohydrate Natarajan, S. Kalyanasundar, A. Suresh, J. Dhas, S. A. Martin Britto Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(2)H(6)NO(2) (+)·C(4)H(3)O(4) (−)·C(2)H(5)NO(2)·H(2)O, the asymmetric unit contains two glycine residues, one protonated and one in the zwitterionic form, a hydrogen fumarate anion and a water mol­ecule. Through N—H⋯O and O—H⋯O hydrogen bonds, mol­ecules assemble in layers parallel to the (10[Image: see text]) plane, one layer of hydrogen fumarate anions alternating with two layers of glycine mol­ecules. In each glycine layer, hydrogen bonds generate an R (4) (4)(19) graph-set motif. Further hydrogen bonds involving the water mol­ecule and the hydrogen fumarate anions result in the formation of a three-dimensional network. International Union of Crystallography 2009-02-04 /pmc/articles/PMC2968449/ /pubmed/21582134 http://dx.doi.org/10.1107/S1600536809001974 Text en © Natarajan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Natarajan, S.
Kalyanasundar, A.
Suresh, J.
Dhas, S. A. Martin Britto
Lakshman, P. L. Nilantha
Glycinium hydrogen fumarate glycine solvate monohydrate
title Glycinium hydrogen fumarate glycine solvate monohydrate
title_full Glycinium hydrogen fumarate glycine solvate monohydrate
title_fullStr Glycinium hydrogen fumarate glycine solvate monohydrate
title_full_unstemmed Glycinium hydrogen fumarate glycine solvate monohydrate
title_short Glycinium hydrogen fumarate glycine solvate monohydrate
title_sort glycinium hydrogen fumarate glycine solvate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968449/
https://www.ncbi.nlm.nih.gov/pubmed/21582134
http://dx.doi.org/10.1107/S1600536809001974
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AT dhassamartinbritto glyciniumhydrogenfumarateglycinesolvatemonohydrate
AT lakshmanplnilantha glyciniumhydrogenfumarateglycinesolvatemonohydrate

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