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trans-(2-Benzoylpyridine-κ(2) N,O)dichlorido[2-(2-pyridylcarbonyl)phenyl-κ(2) C (1),N]iridium(III) dichloromethane solvate
The title compound, [Ir(C(12)H(8)NO)Cl(2)(C(12)H(9)NO)]·CH(2)Cl(2), which was obtained from the reaction of iridium(III) chloride trihydrate and 2-benzoylpyridine, contains an Ir(III) atom coordinated by two N, one O, one C and two Cl atoms in trans positions, forming a distorted octahedral enviro...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968456/ https://www.ncbi.nlm.nih.gov/pubmed/21582057 http://dx.doi.org/10.1107/S1600536809004322 |
| _version_ | 1782189882077085696 |
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| author | Hsueh, Mao-Lin Yang, Cheng-Hsien |
| author_facet | Hsueh, Mao-Lin Yang, Cheng-Hsien |
| author_sort | Hsueh, Mao-Lin |
| collection | PubMed |
| description | The title compound, [Ir(C(12)H(8)NO)Cl(2)(C(12)H(9)NO)]·CH(2)Cl(2), which was obtained from the reaction of iridium(III) chloride trihydrate and 2-benzoylpyridine, contains an Ir(III) atom coordinated by two N, one O, one C and two Cl atoms in trans positions, forming a distorted octahedral environment. The solvent molecule CH(2)Cl(2) is disordered over two positions with an occupancy of 0.8:0.2. |
| format | Text |
| id | pubmed-2968456 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29684562010-12-30 trans-(2-Benzoylpyridine-κ(2) N,O)dichlorido[2-(2-pyridylcarbonyl)phenyl-κ(2) C (1),N]iridium(III) dichloromethane solvate Hsueh, Mao-Lin Yang, Cheng-Hsien Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ir(C(12)H(8)NO)Cl(2)(C(12)H(9)NO)]·CH(2)Cl(2), which was obtained from the reaction of iridium(III) chloride trihydrate and 2-benzoylpyridine, contains an Ir(III) atom coordinated by two N, one O, one C and two Cl atoms in trans positions, forming a distorted octahedral environment. The solvent molecule CH(2)Cl(2) is disordered over two positions with an occupancy of 0.8:0.2. International Union of Crystallography 2009-02-13 /pmc/articles/PMC2968456/ /pubmed/21582057 http://dx.doi.org/10.1107/S1600536809004322 Text en © Hsueh and Yang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hsueh, Mao-Lin Yang, Cheng-Hsien trans-(2-Benzoylpyridine-κ(2) N,O)dichlorido[2-(2-pyridylcarbonyl)phenyl-κ(2) C (1),N]iridium(III) dichloromethane solvate |
| title |
trans-(2-Benzoylpyridine-κ(2)
N,O)dichlorido[2-(2-pyridylcarbonyl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane solvate |
| title_full |
trans-(2-Benzoylpyridine-κ(2)
N,O)dichlorido[2-(2-pyridylcarbonyl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane solvate |
| title_fullStr |
trans-(2-Benzoylpyridine-κ(2)
N,O)dichlorido[2-(2-pyridylcarbonyl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane solvate |
| title_full_unstemmed |
trans-(2-Benzoylpyridine-κ(2)
N,O)dichlorido[2-(2-pyridylcarbonyl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane solvate |
| title_short |
trans-(2-Benzoylpyridine-κ(2)
N,O)dichlorido[2-(2-pyridylcarbonyl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane solvate |
| title_sort | trans-(2-benzoylpyridine-κ(2)
n,o)dichlorido[2-(2-pyridylcarbonyl)phenyl-κ(2)
c
(1),n]iridium(iii) dichloromethane solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968456/ https://www.ncbi.nlm.nih.gov/pubmed/21582057 http://dx.doi.org/10.1107/S1600536809004322 |
| work_keys_str_mv | AT hsuehmaolin trans2benzoylpyridinek2nodichlorido22pyridylcarbonylphenylk2c1niridiumiiidichloromethanesolvate AT yangchenghsien trans2benzoylpyridinek2nodichlorido22pyridylcarbonylphenylk2c1niridiumiiidichloromethanesolvate |