rac-(2R*,3S*,5S*,6R*,7S*,8S*)-7,8-Dichloro­bicyclo­[2.2.2]octane-2,3,5,6-tetrayl tetra­acetate

The title compound, C(16)H(20)Cl(2)O(8), contains a central bicyclo­[2.2.2]octane skeleton with slightly twisted conformation. In this structure, the C—C bond lengths are in the range 1.525 (2)–1.552 (2) Å. Two sides of this skeleton have cis,cis acet­oxy substituents and the Cl atoms have a trans a...

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Detalles Bibliográficos
Autores principales: Şahin, Ertan, Baran, Arif, Balcı, Metin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968458/
https://www.ncbi.nlm.nih.gov/pubmed/21582188
http://dx.doi.org/10.1107/S160053680900484X
Descripción
Sumario:The title compound, C(16)H(20)Cl(2)O(8), contains a central bicyclo­[2.2.2]octane skeleton with slightly twisted conformation. In this structure, the C—C bond lengths are in the range 1.525 (2)–1.552 (2) Å. Two sides of this skeleton have cis,cis acet­oxy substituents and the Cl atoms have a trans arrangement. An extensive network of weak C—H⋯O interactions stabilizes the crystal structure.

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