1,4-Bis(fluoro­meth­yl)benzene

The title compound, C(8)H(8)F(2), lies across a crystallographic inversion centre. The structure features short C⋯F [2.8515 (18) Å] and F⋯F [2.490 (4) Å] contacts, which are significantly shorter than the sum of the van der Waals radii of these atoms. The F atom and methyl­ene H atoms are disordered...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kia, Reza, Patil, P. S., Dharmaprakash, S. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968459/
https://www.ncbi.nlm.nih.gov/pubmed/21582131
http://dx.doi.org/10.1107/S1600536809003730
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author Fun, Hoong-Kun
Kia, Reza
Patil, P. S.
Dharmaprakash, S. M.
author_facet Fun, Hoong-Kun
Kia, Reza
Patil, P. S.
Dharmaprakash, S. M.
author_sort Fun, Hoong-Kun
collection PubMed
description The title compound, C(8)H(8)F(2), lies across a crystallographic inversion centre. The structure features short C⋯F [2.8515 (18) Å] and F⋯F [2.490 (4) Å] contacts, which are significantly shorter than the sum of the van der Waals radii of these atoms. The F atom and methyl­ene H atoms are disordered over two positions with a site-occupancy ratio of 0.633 (3):0.367 (3). In the crystal structure, inter­molecular C—H⋯F inter­actions link neighboring mol­ecules into infinite chains along the b axis. In addition, C—H⋯π inter­actions link these mol­ecules along [10[Image: see text]], forming a two-dimensional network parallel to (101).
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spelling pubmed-29684592010-12-30 1,4-Bis(fluoro­meth­yl)benzene Fun, Hoong-Kun Kia, Reza Patil, P. S. Dharmaprakash, S. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(8)H(8)F(2), lies across a crystallographic inversion centre. The structure features short C⋯F [2.8515 (18) Å] and F⋯F [2.490 (4) Å] contacts, which are significantly shorter than the sum of the van der Waals radii of these atoms. The F atom and methyl­ene H atoms are disordered over two positions with a site-occupancy ratio of 0.633 (3):0.367 (3). In the crystal structure, inter­molecular C—H⋯F inter­actions link neighboring mol­ecules into infinite chains along the b axis. In addition, C—H⋯π inter­actions link these mol­ecules along [10[Image: see text]], forming a two-dimensional network parallel to (101). International Union of Crystallography 2009-02-04 /pmc/articles/PMC2968459/ /pubmed/21582131 http://dx.doi.org/10.1107/S1600536809003730 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kia, Reza
Patil, P. S.
Dharmaprakash, S. M.
1,4-Bis(fluoro­meth­yl)benzene
title 1,4-Bis(fluoro­meth­yl)benzene
title_full 1,4-Bis(fluoro­meth­yl)benzene
title_fullStr 1,4-Bis(fluoro­meth­yl)benzene
title_full_unstemmed 1,4-Bis(fluoro­meth­yl)benzene
title_short 1,4-Bis(fluoro­meth­yl)benzene
title_sort 1,4-bis(fluoro­meth­yl)benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968459/
https://www.ncbi.nlm.nih.gov/pubmed/21582131
http://dx.doi.org/10.1107/S1600536809003730
work_keys_str_mv AT funhoongkun 14bisfluoromethylbenzene
AT kiareza 14bisfluoromethylbenzene
AT patilps 14bisfluoromethylbenzene
AT dharmaprakashsm 14bisfluoromethylbenzene

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