Ferrocenylbutadiyne

The title compound, [Fe(C(5)H(5))(C(9)H(5))], crystallizes in a form of a π–π-stacked assembly formed as a result of strong inter­molecular π–π inter­actions between (a) the triple bonds of two neighboring butadiyne substituents overlapping in a ‘head-to-tail’ fashion [characterized by C⋯C short contacts of 3.622 (5), 3.567 (6) and 3.556 (6) Å] and (b) the triple bonds of the butadiyne substituent and substituted cyclo­pendadiene ring of neighboring mol­ecules [C⋯C = 3.474 (5) and 3.492 (6) Å]. The linear butadiyne substituent has alternating C—C triple and single bonds, while the unsubstituted cyclo­penta­diene ring is slightly positionally disordered (although the structure reported here was solved as non-disordered) and retains a close to eclipsed conformation.