Poly[dichloridobis[μ-1-(4-pyridylmeth­yl)-1H-1,2,4-triazole]copper(II)]

The title coordination polymer, [CuCl(2)(C(8)H(8)N(4))(2)](n), arose from a layer-separated diffusion synthesis at room temperature. The Cu atom (site symmetry [Image: see text]) is coordinated by two chloride ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted...

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Detalles Bibliográficos
Autores principales: Li, Zhu-Lai, Wang, Jian, Xu, Xiu-Zhi, Ye, Xiao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968461/
https://www.ncbi.nlm.nih.gov/pubmed/21582107
http://dx.doi.org/10.1107/S160053680900645X
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author Li, Zhu-Lai
Wang, Jian
Xu, Xiu-Zhi
Ye, Xiao
author_facet Li, Zhu-Lai
Wang, Jian
Xu, Xiu-Zhi
Ye, Xiao
author_sort Li, Zhu-Lai
collection PubMed
description The title coordination polymer, [CuCl(2)(C(8)H(8)N(4))(2)](n), arose from a layer-separated diffusion synthesis at room temperature. The Cu atom (site symmetry [Image: see text]) is coordinated by two chloride ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted trans-CuCl(2)N(4) octa­hedral arrangement. The bridging 1-(4-pyridylmeth­yl)-1H-1,2,4-triazole ligands [dihedral angle between the triazole and pyridine rings = 68.08 (8)°] result in a two-dimensional 4(4) sheet structure in the crystal.
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spelling pubmed-29684612010-12-30 Poly[dichloridobis[μ-1-(4-pyridylmeth­yl)-1H-1,2,4-triazole]copper(II)] Li, Zhu-Lai Wang, Jian Xu, Xiu-Zhi Ye, Xiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title coordination polymer, [CuCl(2)(C(8)H(8)N(4))(2)](n), arose from a layer-separated diffusion synthesis at room temperature. The Cu atom (site symmetry [Image: see text]) is coordinated by two chloride ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted trans-CuCl(2)N(4) octa­hedral arrangement. The bridging 1-(4-pyridylmeth­yl)-1H-1,2,4-triazole ligands [dihedral angle between the triazole and pyridine rings = 68.08 (8)°] result in a two-dimensional 4(4) sheet structure in the crystal. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968461/ /pubmed/21582107 http://dx.doi.org/10.1107/S160053680900645X Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Zhu-Lai
Wang, Jian
Xu, Xiu-Zhi
Ye, Xiao
Poly[dichloridobis[μ-1-(4-pyridylmeth­yl)-1H-1,2,4-triazole]copper(II)]
title Poly[dichloridobis[μ-1-(4-pyridylmeth­yl)-1H-1,2,4-triazole]copper(II)]
title_full Poly[dichloridobis[μ-1-(4-pyridylmeth­yl)-1H-1,2,4-triazole]copper(II)]
title_fullStr Poly[dichloridobis[μ-1-(4-pyridylmeth­yl)-1H-1,2,4-triazole]copper(II)]
title_full_unstemmed Poly[dichloridobis[μ-1-(4-pyridylmeth­yl)-1H-1,2,4-triazole]copper(II)]
title_short Poly[dichloridobis[μ-1-(4-pyridylmeth­yl)-1H-1,2,4-triazole]copper(II)]
title_sort poly[dichloridobis[μ-1-(4-pyridylmeth­yl)-1h-1,2,4-triazole]copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968461/
https://www.ncbi.nlm.nih.gov/pubmed/21582107
http://dx.doi.org/10.1107/S160053680900645X
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