Oxybis(dimesitylborane) dichloro­methane hemisolvate

The title compound, C(36)H(44)B(2)O·0.5CH(2)Cl(2), contains an almost linear O—B—O linkage [177.23 (15)°] and approximately orthogonal [interplanar angles 89.49 (5) and 80.77 (4)°] trigonal planar B centers, consistent with the previously reported non-solvated structure [Cardinet al. (1983). J. Chem...

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Detalles Bibliográficos
Autores principales: Son, Jung-Ho, Hoefelmeyer, James D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968469/
https://www.ncbi.nlm.nih.gov/pubmed/21582141
http://dx.doi.org/10.1107/S160053680804275X
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author Son, Jung-Ho
Hoefelmeyer, James D.
author_facet Son, Jung-Ho
Hoefelmeyer, James D.
author_sort Son, Jung-Ho
collection PubMed
description The title compound, C(36)H(44)B(2)O·0.5CH(2)Cl(2), contains an almost linear O—B—O linkage [177.23 (15)°] and approximately orthogonal [interplanar angles 89.49 (5) and 80.77 (4)°] trigonal planar B centers, consistent with the previously reported non-solvated structure [Cardinet al. (1983). J. Chem. Res. (S), p. 93]. Inter­molecular C—H⋯π inter­actions exist between mesityl groups, with a C—H⋯centroid separation of 3.6535 (18) Å. The dichloromethane mol­ecules lie on twofold rotation axes.
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spelling pubmed-29684692010-12-30 Oxybis(dimesitylborane) dichloro­methane hemisolvate Son, Jung-Ho Hoefelmeyer, James D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(36)H(44)B(2)O·0.5CH(2)Cl(2), contains an almost linear O—B—O linkage [177.23 (15)°] and approximately orthogonal [interplanar angles 89.49 (5) and 80.77 (4)°] trigonal planar B centers, consistent with the previously reported non-solvated structure [Cardinet al. (1983). J. Chem. Res. (S), p. 93]. Inter­molecular C—H⋯π inter­actions exist between mesityl groups, with a C—H⋯centroid separation of 3.6535 (18) Å. The dichloromethane mol­ecules lie on twofold rotation axes. International Union of Crystallography 2009-02-06 /pmc/articles/PMC2968469/ /pubmed/21582141 http://dx.doi.org/10.1107/S160053680804275X Text en © Son and Hoefelmeyer 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Son, Jung-Ho
Hoefelmeyer, James D.
Oxybis(dimesitylborane) dichloro­methane hemisolvate
title Oxybis(dimesitylborane) dichloro­methane hemisolvate
title_full Oxybis(dimesitylborane) dichloro­methane hemisolvate
title_fullStr Oxybis(dimesitylborane) dichloro­methane hemisolvate
title_full_unstemmed Oxybis(dimesitylborane) dichloro­methane hemisolvate
title_short Oxybis(dimesitylborane) dichloro­methane hemisolvate
title_sort oxybis(dimesitylborane) dichloro­methane hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968469/
https://www.ncbi.nlm.nih.gov/pubmed/21582141
http://dx.doi.org/10.1107/S160053680804275X
work_keys_str_mv AT sonjungho oxybisdimesitylboranedichloromethanehemisolvate
AT hoefelmeyerjamesd oxybisdimesitylboranedichloromethanehemisolvate

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