Monomers, dimers, and trimers of [Au(CN)(2)](−) in a Ba(diaza-18-crown-6)(2+) coordination polymer

The structure of the title compound, poly[triaquatetra-μ-cyanido-tetracyanidobis­(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)di­barium(II)tetra­gold(I)], [Au(4)Ba(2)(CN)(8)(C(12)H(26)N(2)O(4))(2)(H(2)O)(3)](n), displays O—H⋯N hydrogen bonding between water molecules and cyano ligands and an u...

Descripción completa

Detalles Bibliográficos
Autores principales: Beavers, Christine M., Paw U, Latisha, Olmstead, Marilyn M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968470/
https://www.ncbi.nlm.nih.gov/pubmed/21582080
http://dx.doi.org/10.1107/S1600536809005285
_version_ 1782189886658314240
author Beavers, Christine M.
Paw U, Latisha
Olmstead, Marilyn M.
author_facet Beavers, Christine M.
Paw U, Latisha
Olmstead, Marilyn M.
author_sort Beavers, Christine M.
collection PubMed
description The structure of the title compound, poly[triaquatetra-μ-cyanido-tetracyanidobis­(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)di­barium(II)tetra­gold(I)], [Au(4)Ba(2)(CN)(8)(C(12)H(26)N(2)O(4))(2)(H(2)O)(3)](n), displays O—H⋯N hydrogen bonding between water molecules and cyano ligands and an unusual pattern of aurophilic inter­actions that yields a monomer, dimer, and trimer of [Au(CN)(2)](−) within the same crystal structure. In two of the five Au positions, the atom resides on a center of inversion. The overall arrangement is that of a coordination polymer assisted by aurophilic and hydrogen-bonded inter­actions.
format Text
id pubmed-2968470
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29684702010-12-30 Monomers, dimers, and trimers of [Au(CN)(2)](−) in a Ba(diaza-18-crown-6)(2+) coordination polymer Beavers, Christine M. Paw U, Latisha Olmstead, Marilyn M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, poly[triaquatetra-μ-cyanido-tetracyanidobis­(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)di­barium(II)tetra­gold(I)], [Au(4)Ba(2)(CN)(8)(C(12)H(26)N(2)O(4))(2)(H(2)O)(3)](n), displays O—H⋯N hydrogen bonding between water molecules and cyano ligands and an unusual pattern of aurophilic inter­actions that yields a monomer, dimer, and trimer of [Au(CN)(2)](−) within the same crystal structure. In two of the five Au positions, the atom resides on a center of inversion. The overall arrangement is that of a coordination polymer assisted by aurophilic and hydrogen-bonded inter­actions. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968470/ /pubmed/21582080 http://dx.doi.org/10.1107/S1600536809005285 Text en © Beavers et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Beavers, Christine M.
Paw U, Latisha
Olmstead, Marilyn M.
Monomers, dimers, and trimers of [Au(CN)(2)](−) in a Ba(diaza-18-crown-6)(2+) coordination polymer
title Monomers, dimers, and trimers of [Au(CN)(2)](−) in a Ba(diaza-18-crown-6)(2+) coordination polymer
title_full Monomers, dimers, and trimers of [Au(CN)(2)](−) in a Ba(diaza-18-crown-6)(2+) coordination polymer
title_fullStr Monomers, dimers, and trimers of [Au(CN)(2)](−) in a Ba(diaza-18-crown-6)(2+) coordination polymer
title_full_unstemmed Monomers, dimers, and trimers of [Au(CN)(2)](−) in a Ba(diaza-18-crown-6)(2+) coordination polymer
title_short Monomers, dimers, and trimers of [Au(CN)(2)](−) in a Ba(diaza-18-crown-6)(2+) coordination polymer
title_sort monomers, dimers, and trimers of [au(cn)(2)](−) in a ba(diaza-18-crown-6)(2+) coordination polymer
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968470/
https://www.ncbi.nlm.nih.gov/pubmed/21582080
http://dx.doi.org/10.1107/S1600536809005285
work_keys_str_mv AT beaverschristinem monomersdimersandtrimersofaucn2inabadiaza18crown62coordinationpolymer
AT pawulatisha monomersdimersandtrimersofaucn2inabadiaza18crown62coordinationpolymer
AT olmsteadmarilynm monomersdimersandtrimersofaucn2inabadiaza18crown62coordinationpolymer

Ejemplares similares