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2-(2-Ammonioethyl)pyridinium hexachloridorhenate(IV)
In the title antiferromagnetic material, (C(7)H(12)N(2))[ReCl(6)], the Néel temperature is observed at 5 K. The salt is stabilized by an extensive network of N—H⋯Cl and C—H⋯Cl hydrogen bonds, where hydrogen-bonded anion chains and characteristic cation–anion motifs are present. Similar systems play...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968471/ https://www.ncbi.nlm.nih.gov/pubmed/21582039 http://dx.doi.org/10.1107/S1600536808044097 |
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author | Kochel, Andrzej |
author_facet | Kochel, Andrzej |
author_sort | Kochel, Andrzej |
collection | PubMed |
description | In the title antiferromagnetic material, (C(7)H(12)N(2))[ReCl(6)], the Néel temperature is observed at 5 K. The salt is stabilized by an extensive network of N—H⋯Cl and C—H⋯Cl hydrogen bonds, where hydrogen-bonded anion chains and characteristic cation–anion motifs are present. Similar systems play an important role in crystal engineering as hydrogen bonds that can transmit magnetic interactions. |
format | Text |
id | pubmed-2968471 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29684712010-12-30 2-(2-Ammonioethyl)pyridinium hexachloridorhenate(IV) Kochel, Andrzej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title antiferromagnetic material, (C(7)H(12)N(2))[ReCl(6)], the Néel temperature is observed at 5 K. The salt is stabilized by an extensive network of N—H⋯Cl and C—H⋯Cl hydrogen bonds, where hydrogen-bonded anion chains and characteristic cation–anion motifs are present. Similar systems play an important role in crystal engineering as hydrogen bonds that can transmit magnetic interactions. International Union of Crystallography 2009-02-04 /pmc/articles/PMC2968471/ /pubmed/21582039 http://dx.doi.org/10.1107/S1600536808044097 Text en © Andrzej Kochel 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kochel, Andrzej 2-(2-Ammonioethyl)pyridinium hexachloridorhenate(IV) |
title | 2-(2-Ammonioethyl)pyridinium hexachloridorhenate(IV) |
title_full | 2-(2-Ammonioethyl)pyridinium hexachloridorhenate(IV) |
title_fullStr | 2-(2-Ammonioethyl)pyridinium hexachloridorhenate(IV) |
title_full_unstemmed | 2-(2-Ammonioethyl)pyridinium hexachloridorhenate(IV) |
title_short | 2-(2-Ammonioethyl)pyridinium hexachloridorhenate(IV) |
title_sort | 2-(2-ammonioethyl)pyridinium hexachloridorhenate(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968471/ https://www.ncbi.nlm.nih.gov/pubmed/21582039 http://dx.doi.org/10.1107/S1600536808044097 |
work_keys_str_mv | AT kochelandrzej 22ammonioethylpyridiniumhexachloridorhenateiv |