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2-(2-Ammonio­ethyl)pyridinium hexa­chloridorhenate(IV)

In the title anti­ferromagnetic material, (C(7)H(12)N(2))[ReCl(6)], the Néel temperature is observed at 5 K. The salt is stabilized by an extensive network of N—H⋯Cl and C—H⋯Cl hydrogen bonds, where hydrogen-bonded anion chains and characteristic cation–anion motifs are present. Similar systems play...

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Detalles Bibliográficos
Autor principal: Kochel, Andrzej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968471/
https://www.ncbi.nlm.nih.gov/pubmed/21582039
http://dx.doi.org/10.1107/S1600536808044097
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author Kochel, Andrzej
author_facet Kochel, Andrzej
author_sort Kochel, Andrzej
collection PubMed
description In the title anti­ferromagnetic material, (C(7)H(12)N(2))[ReCl(6)], the Néel temperature is observed at 5 K. The salt is stabilized by an extensive network of N—H⋯Cl and C—H⋯Cl hydrogen bonds, where hydrogen-bonded anion chains and characteristic cation–anion motifs are present. Similar systems play an important role in crystal engineering as hydrogen bonds that can transmit magnetic inter­actions.
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spelling pubmed-29684712010-12-30 2-(2-Ammonio­ethyl)pyridinium hexa­chloridorhenate(IV) Kochel, Andrzej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title anti­ferromagnetic material, (C(7)H(12)N(2))[ReCl(6)], the Néel temperature is observed at 5 K. The salt is stabilized by an extensive network of N—H⋯Cl and C—H⋯Cl hydrogen bonds, where hydrogen-bonded anion chains and characteristic cation–anion motifs are present. Similar systems play an important role in crystal engineering as hydrogen bonds that can transmit magnetic inter­actions. International Union of Crystallography 2009-02-04 /pmc/articles/PMC2968471/ /pubmed/21582039 http://dx.doi.org/10.1107/S1600536808044097 Text en © Andrzej Kochel 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kochel, Andrzej
2-(2-Ammonio­ethyl)pyridinium hexa­chloridorhenate(IV)
title 2-(2-Ammonio­ethyl)pyridinium hexa­chloridorhenate(IV)
title_full 2-(2-Ammonio­ethyl)pyridinium hexa­chloridorhenate(IV)
title_fullStr 2-(2-Ammonio­ethyl)pyridinium hexa­chloridorhenate(IV)
title_full_unstemmed 2-(2-Ammonio­ethyl)pyridinium hexa­chloridorhenate(IV)
title_short 2-(2-Ammonio­ethyl)pyridinium hexa­chloridorhenate(IV)
title_sort 2-(2-ammonio­ethyl)pyridinium hexa­chloridorhenate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968471/
https://www.ncbi.nlm.nih.gov/pubmed/21582039
http://dx.doi.org/10.1107/S1600536808044097
work_keys_str_mv AT kochelandrzej 22ammonioethylpyridiniumhexachloridorhenateiv