1,3-Bis[(6-methyl-2-pyrid­yl)meth­yl]imidazolium bromide

The title compound, C(17)H(19)N(4) (+)·Br(−), is built up from 1,3-bis­[(6-methyl-2-pyridin­yl)meth­yl]imidazolium cations and bromide anions. Each of two 6-methyl-2-pyridyl rings is rotated out of the imidazole plane, making dihedral angles of 79.90 (9) and 86.40 (9)°. The packing is consolidated b...

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Detalles Bibliográficos
Autores principales: Kim, Ga Young, Park, Sang-Kyu, Lee, Dong-Heon, Park, Gyungse
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968481/
https://www.ncbi.nlm.nih.gov/pubmed/21582286
http://dx.doi.org/10.1107/S1600536809006710
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author Kim, Ga Young
Park, Sang-Kyu
Lee, Dong-Heon
Park, Gyungse
author_facet Kim, Ga Young
Park, Sang-Kyu
Lee, Dong-Heon
Park, Gyungse
author_sort Kim, Ga Young
collection PubMed
description The title compound, C(17)H(19)N(4) (+)·Br(−), is built up from 1,3-bis­[(6-methyl-2-pyridin­yl)meth­yl]imidazolium cations and bromide anions. Each of two 6-methyl-2-pyridyl rings is rotated out of the imidazole plane, making dihedral angles of 79.90 (9) and 86.40 (9)°. The packing is consolidated by aromatic π–π inter­actions between the pyridine rings of neighbouring mol­ecules [centroid–centroid distance = 3.554 (2) Å] and by weak C—H⋯N and C—H⋯Br hydrogen bonds.
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spelling pubmed-29684812010-12-30 1,3-Bis[(6-methyl-2-pyrid­yl)meth­yl]imidazolium bromide Kim, Ga Young Park, Sang-Kyu Lee, Dong-Heon Park, Gyungse Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(19)N(4) (+)·Br(−), is built up from 1,3-bis­[(6-methyl-2-pyridin­yl)meth­yl]imidazolium cations and bromide anions. Each of two 6-methyl-2-pyridyl rings is rotated out of the imidazole plane, making dihedral angles of 79.90 (9) and 86.40 (9)°. The packing is consolidated by aromatic π–π inter­actions between the pyridine rings of neighbouring mol­ecules [centroid–centroid distance = 3.554 (2) Å] and by weak C—H⋯N and C—H⋯Br hydrogen bonds. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968481/ /pubmed/21582286 http://dx.doi.org/10.1107/S1600536809006710 Text en © Kim et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kim, Ga Young
Park, Sang-Kyu
Lee, Dong-Heon
Park, Gyungse
1,3-Bis[(6-methyl-2-pyrid­yl)meth­yl]imidazolium bromide
title 1,3-Bis[(6-methyl-2-pyrid­yl)meth­yl]imidazolium bromide
title_full 1,3-Bis[(6-methyl-2-pyrid­yl)meth­yl]imidazolium bromide
title_fullStr 1,3-Bis[(6-methyl-2-pyrid­yl)meth­yl]imidazolium bromide
title_full_unstemmed 1,3-Bis[(6-methyl-2-pyrid­yl)meth­yl]imidazolium bromide
title_short 1,3-Bis[(6-methyl-2-pyrid­yl)meth­yl]imidazolium bromide
title_sort 1,3-bis[(6-methyl-2-pyrid­yl)meth­yl]imidazolium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968481/
https://www.ncbi.nlm.nih.gov/pubmed/21582286
http://dx.doi.org/10.1107/S1600536809006710
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