Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κ(2) N,N′)cobalt(II)]

In the title compound, [CoCl(2)(C(10)H(8)N(2)S)(2)](n), the Co(II) atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octa­hedral geometry. The bridging bidentate di-...

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Detalles Bibliográficos
Autores principales: Wang, Jian-Ge, Qin, Jian-Hua, Zhang, Gui-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968483/
https://www.ncbi.nlm.nih.gov/pubmed/21582041
http://dx.doi.org/10.1107/S1600536809001676
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author Wang, Jian-Ge
Qin, Jian-Hua
Zhang, Gui-Ying
author_facet Wang, Jian-Ge
Qin, Jian-Hua
Zhang, Gui-Ying
author_sort Wang, Jian-Ge
collection PubMed
description In the title compound, [CoCl(2)(C(10)H(8)N(2)S)(2)](n), the Co(II) atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octa­hedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the Co(II) centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intra­molecular C—H⋯N and C—H⋯Cl hydrogen bonds.
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spelling pubmed-29684832010-12-30 Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κ(2) N,N′)cobalt(II)] Wang, Jian-Ge Qin, Jian-Hua Zhang, Gui-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(10)H(8)N(2)S)(2)](n), the Co(II) atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octa­hedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the Co(II) centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intra­molecular C—H⋯N and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2009-02-04 /pmc/articles/PMC2968483/ /pubmed/21582041 http://dx.doi.org/10.1107/S1600536809001676 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jian-Ge
Qin, Jian-Hua
Zhang, Gui-Ying
Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κ(2) N,N′)cobalt(II)]
title Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κ(2) N,N′)cobalt(II)]
title_full Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κ(2) N,N′)cobalt(II)]
title_fullStr Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κ(2) N,N′)cobalt(II)]
title_full_unstemmed Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κ(2) N,N′)cobalt(II)]
title_short Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κ(2) N,N′)cobalt(II)]
title_sort poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κ(2) n,n′)cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968483/
https://www.ncbi.nlm.nih.gov/pubmed/21582041
http://dx.doi.org/10.1107/S1600536809001676
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