Synthesis, crystal structure and Raman spectrum of K(2)[(Pt(2))(HPO(4))(4)(H(2)O)(2)] containing (Pt(2))(6+) ions

In the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis­[aqua­platinum(III)](Pt—Pt), K(2)[Pt(2)(HPO(4))(4)(H(2)O)(2)], the (Pt(2))(6+) dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892 (5) Å. The pottassium ions are seven-f...

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Detalles Bibliográficos
Autores principales: Panagiotidis, Kosta, Glaum, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968486/
https://www.ncbi.nlm.nih.gov/pubmed/21582035
http://dx.doi.org/10.1107/S1600536809005601
Descripción
Sumario:In the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis­[aqua­platinum(III)](Pt—Pt), K(2)[Pt(2)(HPO(4))(4)(H(2)O)(2)], the (Pt(2))(6+) dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892 (5) Å. The pottassium ions are seven-fold coordinated by hydrogenphosphate groups. In the crystal, O—H⋯O hydrogen bonds help to establish the packing. The Raman spectrum was recorded.

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