Synthesis, crystal structure and Raman spectrum of K(2)[(Pt(2))(HPO(4))(4)(H(2)O)(2)] containing (Pt(2))(6+) ions

In the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis­[aqua­platinum(III)](Pt—Pt), K(2)[Pt(2)(HPO(4))(4)(H(2)O)(2)], the (Pt(2))(6+) dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892 (5) Å. The pottassium ions are seven-f...

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Detalles Bibliográficos
Autores principales: Panagiotidis, Kosta, Glaum, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968486/
https://www.ncbi.nlm.nih.gov/pubmed/21582035
http://dx.doi.org/10.1107/S1600536809005601
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author Panagiotidis, Kosta
Glaum, Robert
author_facet Panagiotidis, Kosta
Glaum, Robert
author_sort Panagiotidis, Kosta
collection PubMed
description In the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis­[aqua­platinum(III)](Pt—Pt), K(2)[Pt(2)(HPO(4))(4)(H(2)O)(2)], the (Pt(2))(6+) dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892 (5) Å. The pottassium ions are seven-fold coordinated by hydrogenphosphate groups. In the crystal, O—H⋯O hydrogen bonds help to establish the packing. The Raman spectrum was recorded.
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spelling pubmed-29684862010-12-30 Synthesis, crystal structure and Raman spectrum of K(2)[(Pt(2))(HPO(4))(4)(H(2)O)(2)] containing (Pt(2))(6+) ions Panagiotidis, Kosta Glaum, Robert Acta Crystallogr Sect E Struct Rep Online Inorganic Papers In the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis­[aqua­platinum(III)](Pt—Pt), K(2)[Pt(2)(HPO(4))(4)(H(2)O)(2)], the (Pt(2))(6+) dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892 (5) Å. The pottassium ions are seven-fold coordinated by hydrogenphosphate groups. In the crystal, O—H⋯O hydrogen bonds help to establish the packing. The Raman spectrum was recorded. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968486/ /pubmed/21582035 http://dx.doi.org/10.1107/S1600536809005601 Text en © Panagiotidis and Glaum 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Panagiotidis, Kosta
Glaum, Robert
Synthesis, crystal structure and Raman spectrum of K(2)[(Pt(2))(HPO(4))(4)(H(2)O)(2)] containing (Pt(2))(6+) ions
title Synthesis, crystal structure and Raman spectrum of K(2)[(Pt(2))(HPO(4))(4)(H(2)O)(2)] containing (Pt(2))(6+) ions
title_full Synthesis, crystal structure and Raman spectrum of K(2)[(Pt(2))(HPO(4))(4)(H(2)O)(2)] containing (Pt(2))(6+) ions
title_fullStr Synthesis, crystal structure and Raman spectrum of K(2)[(Pt(2))(HPO(4))(4)(H(2)O)(2)] containing (Pt(2))(6+) ions
title_full_unstemmed Synthesis, crystal structure and Raman spectrum of K(2)[(Pt(2))(HPO(4))(4)(H(2)O)(2)] containing (Pt(2))(6+) ions
title_short Synthesis, crystal structure and Raman spectrum of K(2)[(Pt(2))(HPO(4))(4)(H(2)O)(2)] containing (Pt(2))(6+) ions
title_sort synthesis, crystal structure and raman spectrum of k(2)[(pt(2))(hpo(4))(4)(h(2)o)(2)] containing (pt(2))(6+) ions
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968486/
https://www.ncbi.nlm.nih.gov/pubmed/21582035
http://dx.doi.org/10.1107/S1600536809005601
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