{6,6′-Dimeth­oxy-2,2′-[naphthalene-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}thio­cyanato­cobalt(III) diethyl ether dichloro­methane solvate

In the title complex, [Co(C(26)H(20)N(2)O(4))(NCS)]·C(4)H(10)O·CH(2)Cl(2), the penta­coordinated Co(III) atom exhibits a distorted square-pyramidal geometry with an N,N′,O,O′ tetra­dentate Schiff base ligand in the basal plane and one thio­cyanate ligand at the apical site. The diethyl ether mol­ecule is located in a cavity provided by four O atoms of the ligand with weak C—H⋯O inter­actions, generating two short O⋯O contact distances [2.766 (3) and 2.745 (3) Å] between the diethyl ether mol­ecule and the ligand. The crystal structure is stabilized by the weak C—H⋯O and C—H⋯N inter­actions and π–π inter­actions between the naphthyl ring system and the benzene ring [centroid–centroid distance = 3.657 (5) Å] and between the two naphthyl ring systems [centroid–centroid distance = 4.305 (2) Å].