[N,N′-Bis(4-bromo­benzyl­idene)-2,2-di­methyl­propane-κ(2) N,N′]iodidocopper(I)

The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7 (3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms...

Descripción completa

Detalles Bibliográficos
Autores principales: Kia, Reza, Fun, Hoong-Kun, Kargar, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968488/
https://www.ncbi.nlm.nih.gov/pubmed/21582073
http://dx.doi.org/10.1107/S1600536809005078
_version_ 1782189891859251200
author Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_facet Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_sort Kia, Reza
collection PubMed
description The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7 (3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu(I) atom. This conformation is required by the crystallographic mirror symmetry. The inter­planar angle between the benzene rings is 74.85 (19)°. The crystal structure exhibits weak inter­molecular C—H⋯π inter­actions, which link the mol­ecules into chains along the b axis.
format Text
id pubmed-2968488
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29684882010-12-30 [N,N′-Bis(4-bromo­benzyl­idene)-2,2-di­methyl­propane-κ(2) N,N′]iodidocopper(I) Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7 (3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu(I) atom. This conformation is required by the crystallographic mirror symmetry. The inter­planar angle between the benzene rings is 74.85 (19)°. The crystal structure exhibits weak inter­molecular C—H⋯π inter­actions, which link the mol­ecules into chains along the b axis. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968488/ /pubmed/21582073 http://dx.doi.org/10.1107/S1600536809005078 Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
[N,N′-Bis(4-bromo­benzyl­idene)-2,2-di­methyl­propane-κ(2) N,N′]iodidocopper(I)
title [N,N′-Bis(4-bromo­benzyl­idene)-2,2-di­methyl­propane-κ(2) N,N′]iodidocopper(I)
title_full [N,N′-Bis(4-bromo­benzyl­idene)-2,2-di­methyl­propane-κ(2) N,N′]iodidocopper(I)
title_fullStr [N,N′-Bis(4-bromo­benzyl­idene)-2,2-di­methyl­propane-κ(2) N,N′]iodidocopper(I)
title_full_unstemmed [N,N′-Bis(4-bromo­benzyl­idene)-2,2-di­methyl­propane-κ(2) N,N′]iodidocopper(I)
title_short [N,N′-Bis(4-bromo­benzyl­idene)-2,2-di­methyl­propane-κ(2) N,N′]iodidocopper(I)
title_sort [n,n′-bis(4-bromo­benzyl­idene)-2,2-di­methyl­propane-κ(2) n,n′]iodidocopper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968488/
https://www.ncbi.nlm.nih.gov/pubmed/21582073
http://dx.doi.org/10.1107/S1600536809005078
work_keys_str_mv AT kiareza nnbis4bromobenzylidene22dimethylpropanek2nniodidocopperi
AT funhoongkun nnbis4bromobenzylidene22dimethylpropanek2nniodidocopperi
AT kargarhadi nnbis4bromobenzylidene22dimethylpropanek2nniodidocopperi

Ejemplares similares