Bis[4-(2-benzyl­idenepropyl­idene­amino)phen­yl] ether

The title compound, C(32)H(28)N(2)O, is a flexible Schiff base displaying a trans configuration across the C=N double bond. It was prepared in high yield by condensation of α-methyl­cinnamaldehyde and bis­(4-amino­phen­yl) ether in methanol at room temperature. The sample, with pseudo-ortho­rhom­bic...

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Detalles Bibliográficos
Autores principales: Movahedi, Mansoor, Hadadzadeh, Hassan, Fejfarova, Karla, Dusek, Michal, Dehno Khalaji, Aliakbar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968496/
https://www.ncbi.nlm.nih.gov/pubmed/21582198
http://dx.doi.org/10.1107/S1600536809005005
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author Movahedi, Mansoor
Hadadzadeh, Hassan
Fejfarova, Karla
Dusek, Michal
Dehno Khalaji, Aliakbar
author_facet Movahedi, Mansoor
Hadadzadeh, Hassan
Fejfarova, Karla
Dusek, Michal
Dehno Khalaji, Aliakbar
author_sort Movahedi, Mansoor
collection PubMed
description The title compound, C(32)H(28)N(2)O, is a flexible Schiff base displaying a trans configuration across the C=N double bond. It was prepared in high yield by condensation of α-methyl­cinnamaldehyde and bis­(4-amino­phen­yl) ether in methanol at room temperature. The sample, with pseudo-ortho­rhom­bic cell parameters, exhibited merohedral twinning by rotation 180° around a*, with a refined twin domain fraction of 0.722 (1). The elongated shape of the elementary cell corresponds to the shape and direction of the mol­ecules. The dihedral angle between the O-linked aromatic rings is 57.86 (8)°.
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spelling pubmed-29684962010-12-30 Bis[4-(2-benzyl­idenepropyl­idene­amino)phen­yl] ether Movahedi, Mansoor Hadadzadeh, Hassan Fejfarova, Karla Dusek, Michal Dehno Khalaji, Aliakbar Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(32)H(28)N(2)O, is a flexible Schiff base displaying a trans configuration across the C=N double bond. It was prepared in high yield by condensation of α-methyl­cinnamaldehyde and bis­(4-amino­phen­yl) ether in methanol at room temperature. The sample, with pseudo-ortho­rhom­bic cell parameters, exhibited merohedral twinning by rotation 180° around a*, with a refined twin domain fraction of 0.722 (1). The elongated shape of the elementary cell corresponds to the shape and direction of the mol­ecules. The dihedral angle between the O-linked aromatic rings is 57.86 (8)°. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968496/ /pubmed/21582198 http://dx.doi.org/10.1107/S1600536809005005 Text en © Movahedi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Movahedi, Mansoor
Hadadzadeh, Hassan
Fejfarova, Karla
Dusek, Michal
Dehno Khalaji, Aliakbar
Bis[4-(2-benzyl­idenepropyl­idene­amino)phen­yl] ether
title Bis[4-(2-benzyl­idenepropyl­idene­amino)phen­yl] ether
title_full Bis[4-(2-benzyl­idenepropyl­idene­amino)phen­yl] ether
title_fullStr Bis[4-(2-benzyl­idenepropyl­idene­amino)phen­yl] ether
title_full_unstemmed Bis[4-(2-benzyl­idenepropyl­idene­amino)phen­yl] ether
title_short Bis[4-(2-benzyl­idenepropyl­idene­amino)phen­yl] ether
title_sort bis[4-(2-benzyl­idenepropyl­idene­amino)phen­yl] ether
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968496/
https://www.ncbi.nlm.nih.gov/pubmed/21582198
http://dx.doi.org/10.1107/S1600536809005005
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