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(4-Chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone
In the title compound, C(20)H(17)ClO(3), the naphthalene and benzene rings form an interplanar angle of 83.30 (8)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring than to the plane of the benzene ring, viz. 55...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968497/ https://www.ncbi.nlm.nih.gov/pubmed/21582202 http://dx.doi.org/10.1107/S1600536809004796 |
Sumario: | In the title compound, C(20)H(17)ClO(3), the naphthalene and benzene rings form an interplanar angle of 83.30 (8)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring than to the plane of the benzene ring, viz. 55.8 (2)° versus 15.8 (2)°. The 4-chlorophenyl groups form a centrosymmetric π–π interaction, with a centroid–centroid distance of 3.829 (1) Å and a lateral offset of 1.758 Å. An intermolecular C—H⋯O interaction is formed between the 4-chlorophenyl group and the O atom of a neighbouring methoxy group, and two very weak C—H⋯π contacts are present. |
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