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(4-Chloro­benzoyl)(2-eth­oxy-7-methoxy­naphthalen-1-yl)methanone

In the title compound, C(20)H(17)ClO(3), the naphthalene and benzene rings form an inter­planar angle of 83.30 (8)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring than to the plane of the benzene ring, viz. 55...

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Detalles Bibliográficos
Autores principales: Mitsui, Ryosuke, Noguchi, Keiichi, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968497/
https://www.ncbi.nlm.nih.gov/pubmed/21582202
http://dx.doi.org/10.1107/S1600536809004796
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author Mitsui, Ryosuke
Noguchi, Keiichi
Yonezawa, Noriyuki
author_facet Mitsui, Ryosuke
Noguchi, Keiichi
Yonezawa, Noriyuki
author_sort Mitsui, Ryosuke
collection PubMed
description In the title compound, C(20)H(17)ClO(3), the naphthalene and benzene rings form an inter­planar angle of 83.30 (8)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring than to the plane of the benzene ring, viz. 55.8 (2)° versus 15.8 (2)°. The 4-chloro­phenyl groups form a centrosymmetric π–π inter­action, with a centroid–centroid distance of 3.829 (1) Å and a lateral offset of 1.758 Å. An inter­molecular C—H⋯O inter­action is formed between the 4-chloro­phenyl group and the O atom of a neighbouring meth­oxy group, and two very weak C—H⋯π contacts are present.
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spelling pubmed-29684972010-12-30 (4-Chloro­benzoyl)(2-eth­oxy-7-methoxy­naphthalen-1-yl)methanone Mitsui, Ryosuke Noguchi, Keiichi Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(17)ClO(3), the naphthalene and benzene rings form an inter­planar angle of 83.30 (8)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring than to the plane of the benzene ring, viz. 55.8 (2)° versus 15.8 (2)°. The 4-chloro­phenyl groups form a centrosymmetric π–π inter­action, with a centroid–centroid distance of 3.829 (1) Å and a lateral offset of 1.758 Å. An inter­molecular C—H⋯O inter­action is formed between the 4-chloro­phenyl group and the O atom of a neighbouring meth­oxy group, and two very weak C—H⋯π contacts are present. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968497/ /pubmed/21582202 http://dx.doi.org/10.1107/S1600536809004796 Text en © Mitsui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mitsui, Ryosuke
Noguchi, Keiichi
Yonezawa, Noriyuki
(4-Chloro­benzoyl)(2-eth­oxy-7-methoxy­naphthalen-1-yl)methanone
title (4-Chloro­benzoyl)(2-eth­oxy-7-methoxy­naphthalen-1-yl)methanone
title_full (4-Chloro­benzoyl)(2-eth­oxy-7-methoxy­naphthalen-1-yl)methanone
title_fullStr (4-Chloro­benzoyl)(2-eth­oxy-7-methoxy­naphthalen-1-yl)methanone
title_full_unstemmed (4-Chloro­benzoyl)(2-eth­oxy-7-methoxy­naphthalen-1-yl)methanone
title_short (4-Chloro­benzoyl)(2-eth­oxy-7-methoxy­naphthalen-1-yl)methanone
title_sort (4-chloro­benzoyl)(2-eth­oxy-7-methoxy­naphthalen-1-yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968497/
https://www.ncbi.nlm.nih.gov/pubmed/21582202
http://dx.doi.org/10.1107/S1600536809004796
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