Cargando…
(4-Chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone
In the title compound, C(20)H(17)ClO(3), the naphthalene and benzene rings form an interplanar angle of 83.30 (8)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring than to the plane of the benzene ring, viz. 55...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968497/ https://www.ncbi.nlm.nih.gov/pubmed/21582202 http://dx.doi.org/10.1107/S1600536809004796 |
_version_ | 1782189894635880448 |
---|---|
author | Mitsui, Ryosuke Noguchi, Keiichi Yonezawa, Noriyuki |
author_facet | Mitsui, Ryosuke Noguchi, Keiichi Yonezawa, Noriyuki |
author_sort | Mitsui, Ryosuke |
collection | PubMed |
description | In the title compound, C(20)H(17)ClO(3), the naphthalene and benzene rings form an interplanar angle of 83.30 (8)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring than to the plane of the benzene ring, viz. 55.8 (2)° versus 15.8 (2)°. The 4-chlorophenyl groups form a centrosymmetric π–π interaction, with a centroid–centroid distance of 3.829 (1) Å and a lateral offset of 1.758 Å. An intermolecular C—H⋯O interaction is formed between the 4-chlorophenyl group and the O atom of a neighbouring methoxy group, and two very weak C—H⋯π contacts are present. |
format | Text |
id | pubmed-2968497 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29684972010-12-30 (4-Chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone Mitsui, Ryosuke Noguchi, Keiichi Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(17)ClO(3), the naphthalene and benzene rings form an interplanar angle of 83.30 (8)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring than to the plane of the benzene ring, viz. 55.8 (2)° versus 15.8 (2)°. The 4-chlorophenyl groups form a centrosymmetric π–π interaction, with a centroid–centroid distance of 3.829 (1) Å and a lateral offset of 1.758 Å. An intermolecular C—H⋯O interaction is formed between the 4-chlorophenyl group and the O atom of a neighbouring methoxy group, and two very weak C—H⋯π contacts are present. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968497/ /pubmed/21582202 http://dx.doi.org/10.1107/S1600536809004796 Text en © Mitsui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Mitsui, Ryosuke Noguchi, Keiichi Yonezawa, Noriyuki (4-Chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone |
title | (4-Chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone |
title_full | (4-Chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone |
title_fullStr | (4-Chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone |
title_full_unstemmed | (4-Chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone |
title_short | (4-Chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone |
title_sort | (4-chlorobenzoyl)(2-ethoxy-7-methoxynaphthalen-1-yl)methanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968497/ https://www.ncbi.nlm.nih.gov/pubmed/21582202 http://dx.doi.org/10.1107/S1600536809004796 |
work_keys_str_mv | AT mitsuiryosuke 4chlorobenzoyl2ethoxy7methoxynaphthalen1ylmethanone AT noguchikeiichi 4chlorobenzoyl2ethoxy7methoxynaphthalen1ylmethanone AT yonezawanoriyuki 4chlorobenzoyl2ethoxy7methoxynaphthalen1ylmethanone |