(4S,5R,6R)-Methyl 4-hydr­oxy-4,5-iso­propyl­idenedioxy-4,5,6,7-tetra­hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl­ate

X-ray crystallography confirmed the structure of the title triazole, C(11)H(15)N(3)O(5), formed from a single-step reaction of a sugar azide with a brominated ylid. The absolute configuration was determined by the use of d-ribose as the starting material. The six-membered ring is in a half-chair con...

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Detalles Bibliográficos
Autores principales: Jenkinson, Sarah F., Fenton, Jennifer R., Booth, K. Victoria, Fleet, George W. J., Watkin, David J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968499/
https://www.ncbi.nlm.nih.gov/pubmed/21582263
http://dx.doi.org/10.1107/S1600536809006357
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author Jenkinson, Sarah F.
Fenton, Jennifer R.
Booth, K. Victoria
Fleet, George W. J.
Watkin, David J.
author_facet Jenkinson, Sarah F.
Fenton, Jennifer R.
Booth, K. Victoria
Fleet, George W. J.
Watkin, David J.
author_sort Jenkinson, Sarah F.
collection PubMed
description X-ray crystallography confirmed the structure of the title triazole, C(11)H(15)N(3)O(5), formed from a single-step reaction of a sugar azide with a brominated ylid. The absolute configuration was determined by the use of d-ribose as the starting material. The six-membered ring is in a half-chair conformation. The crystal structure exists as chains of O—H⋯O hydrogen-bonded moleclues running parallel to the b axis.
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spelling pubmed-29684992010-12-30 (4S,5R,6R)-Methyl 4-hydr­oxy-4,5-iso­propyl­idenedioxy-4,5,6,7-tetra­hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl­ate Jenkinson, Sarah F. Fenton, Jennifer R. Booth, K. Victoria Fleet, George W. J. Watkin, David J. Acta Crystallogr Sect E Struct Rep Online Organic Papers X-ray crystallography confirmed the structure of the title triazole, C(11)H(15)N(3)O(5), formed from a single-step reaction of a sugar azide with a brominated ylid. The absolute configuration was determined by the use of d-ribose as the starting material. The six-membered ring is in a half-chair conformation. The crystal structure exists as chains of O—H⋯O hydrogen-bonded moleclues running parallel to the b axis. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968499/ /pubmed/21582263 http://dx.doi.org/10.1107/S1600536809006357 Text en © Jenkinson et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jenkinson, Sarah F.
Fenton, Jennifer R.
Booth, K. Victoria
Fleet, George W. J.
Watkin, David J.
(4S,5R,6R)-Methyl 4-hydr­oxy-4,5-iso­propyl­idenedioxy-4,5,6,7-tetra­hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl­ate
title (4S,5R,6R)-Methyl 4-hydr­oxy-4,5-iso­propyl­idenedioxy-4,5,6,7-tetra­hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl­ate
title_full (4S,5R,6R)-Methyl 4-hydr­oxy-4,5-iso­propyl­idenedioxy-4,5,6,7-tetra­hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl­ate
title_fullStr (4S,5R,6R)-Methyl 4-hydr­oxy-4,5-iso­propyl­idenedioxy-4,5,6,7-tetra­hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl­ate
title_full_unstemmed (4S,5R,6R)-Methyl 4-hydr­oxy-4,5-iso­propyl­idenedioxy-4,5,6,7-tetra­hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl­ate
title_short (4S,5R,6R)-Methyl 4-hydr­oxy-4,5-iso­propyl­idenedioxy-4,5,6,7-tetra­hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl­ate
title_sort (4s,5r,6r)-methyl 4-hydr­oxy-4,5-iso­propyl­idenedioxy-4,5,6,7-tetra­hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968499/
https://www.ncbi.nlm.nih.gov/pubmed/21582263
http://dx.doi.org/10.1107/S1600536809006357
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