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Bis{2-meth­oxy-6-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate

In the title complex, [Mn(C(12)H(16)NO(5))(2)]·2CH(3)OH·0.5H(2)O, the Mn(II) atom has a distorted octa­hedral coordination geometry in which two N atoms from two 6-meth­oxy-2-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolate ligands adopt a trans arrangement. The Mn—O(H) bonds (mean length 2.134...

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Detalles Bibliográficos
Autores principales: Zhang, Xiutang, Wei, Peihai, Dou, Jianmin, Li, Bin, Hu, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968500/
https://www.ncbi.nlm.nih.gov/pubmed/21582076
http://dx.doi.org/10.1107/S1600536809005364
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author Zhang, Xiutang
Wei, Peihai
Dou, Jianmin
Li, Bin
Hu, Bo
author_facet Zhang, Xiutang
Wei, Peihai
Dou, Jianmin
Li, Bin
Hu, Bo
author_sort Zhang, Xiutang
collection PubMed
description In the title complex, [Mn(C(12)H(16)NO(5))(2)]·2CH(3)OH·0.5H(2)O, the Mn(II) atom has a distorted octa­hedral coordination geometry in which two N atoms from two 6-meth­oxy-2-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolate ligands adopt a trans arrangement. The Mn—O(H) bonds (mean length 2.134 Å) are significantly longer than the Mn—O and Mn—N bonds (mean length 2.011 and 2.027 Å, respectively), and the dihedral angle between the mean planes through the aromatic rings of the two ligands is 76.8 (1)°. A complex network of O—H⋯O hydrogen bonds is formed between the complexes and the uncoordinated methanol and water mol­ecules. The C and O atoms of one C—OH group are disordered with equal occupancies.
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spelling pubmed-29685002010-12-30 Bis{2-meth­oxy-6-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate Zhang, Xiutang Wei, Peihai Dou, Jianmin Li, Bin Hu, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(12)H(16)NO(5))(2)]·2CH(3)OH·0.5H(2)O, the Mn(II) atom has a distorted octa­hedral coordination geometry in which two N atoms from two 6-meth­oxy-2-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolate ligands adopt a trans arrangement. The Mn—O(H) bonds (mean length 2.134 Å) are significantly longer than the Mn—O and Mn—N bonds (mean length 2.011 and 2.027 Å, respectively), and the dihedral angle between the mean planes through the aromatic rings of the two ligands is 76.8 (1)°. A complex network of O—H⋯O hydrogen bonds is formed between the complexes and the uncoordinated methanol and water mol­ecules. The C and O atoms of one C—OH group are disordered with equal occupancies. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968500/ /pubmed/21582076 http://dx.doi.org/10.1107/S1600536809005364 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiutang
Wei, Peihai
Dou, Jianmin
Li, Bin
Hu, Bo
Bis{2-meth­oxy-6-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate
title Bis{2-meth­oxy-6-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate
title_full Bis{2-meth­oxy-6-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate
title_fullStr Bis{2-meth­oxy-6-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate
title_full_unstemmed Bis{2-meth­oxy-6-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate
title_short Bis{2-meth­oxy-6-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate
title_sort bis{2-meth­oxy-6-[tris­(hydroxy­meth­yl)methyl­imino­meth­yl]phenolato-κ(3) o,n,o′}manganese(ii) dimethanol solvate hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968500/
https://www.ncbi.nlm.nih.gov/pubmed/21582076
http://dx.doi.org/10.1107/S1600536809005364
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