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Bis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate
In the title complex, [Mn(C(12)H(16)NO(5))(2)]·2CH(3)OH·0.5H(2)O, the Mn(II) atom has a distorted octahedral coordination geometry in which two N atoms from two 6-methoxy-2-[tris(hydroxymethyl)methyliminomethyl]phenolate ligands adopt a trans arrangement. The Mn—O(H) bonds (mean length 2.134...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968500/ https://www.ncbi.nlm.nih.gov/pubmed/21582076 http://dx.doi.org/10.1107/S1600536809005364 |
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author | Zhang, Xiutang Wei, Peihai Dou, Jianmin Li, Bin Hu, Bo |
author_facet | Zhang, Xiutang Wei, Peihai Dou, Jianmin Li, Bin Hu, Bo |
author_sort | Zhang, Xiutang |
collection | PubMed |
description | In the title complex, [Mn(C(12)H(16)NO(5))(2)]·2CH(3)OH·0.5H(2)O, the Mn(II) atom has a distorted octahedral coordination geometry in which two N atoms from two 6-methoxy-2-[tris(hydroxymethyl)methyliminomethyl]phenolate ligands adopt a trans arrangement. The Mn—O(H) bonds (mean length 2.134 Å) are significantly longer than the Mn—O and Mn—N bonds (mean length 2.011 and 2.027 Å, respectively), and the dihedral angle between the mean planes through the aromatic rings of the two ligands is 76.8 (1)°. A complex network of O—H⋯O hydrogen bonds is formed between the complexes and the uncoordinated methanol and water molecules. The C and O atoms of one C—OH group are disordered with equal occupancies. |
format | Text |
id | pubmed-2968500 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29685002010-12-30 Bis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate Zhang, Xiutang Wei, Peihai Dou, Jianmin Li, Bin Hu, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(12)H(16)NO(5))(2)]·2CH(3)OH·0.5H(2)O, the Mn(II) atom has a distorted octahedral coordination geometry in which two N atoms from two 6-methoxy-2-[tris(hydroxymethyl)methyliminomethyl]phenolate ligands adopt a trans arrangement. The Mn—O(H) bonds (mean length 2.134 Å) are significantly longer than the Mn—O and Mn—N bonds (mean length 2.011 and 2.027 Å, respectively), and the dihedral angle between the mean planes through the aromatic rings of the two ligands is 76.8 (1)°. A complex network of O—H⋯O hydrogen bonds is formed between the complexes and the uncoordinated methanol and water molecules. The C and O atoms of one C—OH group are disordered with equal occupancies. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968500/ /pubmed/21582076 http://dx.doi.org/10.1107/S1600536809005364 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Xiutang Wei, Peihai Dou, Jianmin Li, Bin Hu, Bo Bis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ(3) O,N,O′}manganese(II) dimethanol solvate hemihydrate |
title | Bis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ(3)
O,N,O′}manganese(II) dimethanol solvate hemihydrate |
title_full | Bis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ(3)
O,N,O′}manganese(II) dimethanol solvate hemihydrate |
title_fullStr | Bis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ(3)
O,N,O′}manganese(II) dimethanol solvate hemihydrate |
title_full_unstemmed | Bis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ(3)
O,N,O′}manganese(II) dimethanol solvate hemihydrate |
title_short | Bis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ(3)
O,N,O′}manganese(II) dimethanol solvate hemihydrate |
title_sort | bis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ(3)
o,n,o′}manganese(ii) dimethanol solvate hemihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968500/ https://www.ncbi.nlm.nih.gov/pubmed/21582076 http://dx.doi.org/10.1107/S1600536809005364 |
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